Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids

doi:10.1039/c6cc01750a

	Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids
	Wu, Guojiao 1; Deng, Yifan 1; Luo, Haiqing 1; Zhou, Junliang 1; Li, Tianjiao 1; Zhang, Yan 1; Wang, Jianbo 1,2
刊名	CHEMICAL COMMUNICATIONS
	2016
卷号	52 期号:30 页码:5266-5268
ISSN号	1359-7345
DOI	10.1039/c6cc01750a
文献子类	Article
英文摘要	alpha-Halo-N-tosylhydrazones are employed as reagents for the formation of multiple carbon-carbon bonds in the three-component reactions. In this transformation, a strategy has been designed to generate the diazo intermediate by using a nucleophile to react with the azoalkene intermediate generated in situ from the alpha-halo-N-tosylhydrazone. The diazo intermediate thus generated further undergoes transition-metal-free C-C bond forming reaction with arylboronic acids.
WOS关键词	SITU GENERATED 1,2-DIAZA-1,3-DIENES ; IN-SITU ; EFFICIENT SYNTHESIS ; CARBONYL-COMPOUNDS ; COUPLING REACTIONS ; BORONIC ACIDS ; AZOALKENES ; CARBENE ; CYCLOADDITION ; INSERTION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000373687400011
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170720]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Minist Educ,BNLMS, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Wu, Guojiao,Deng, Yifan,Luo, Haiqing,et al. Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids[J]. CHEMICAL COMMUNICATIONS,2016,52(30):5266-5268.
APA	Wu, Guojiao.,Deng, Yifan.,Luo, Haiqing.,Zhou, Junliang.,Li, Tianjiao.,...&Wang, Jianbo.(2016).Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids.CHEMICAL COMMUNICATIONS,52(30),5266-5268.
MLA	Wu, Guojiao,et al."Transition-metal-free cascade reaction of alpha-halo-N-tosylhydrazones, indoles and arylboronic acids".CHEMICAL COMMUNICATIONS 52.30(2016):5266-5268.