Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters

doi:10.1002/adsc.201500709

	Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters
	Li, Yunyun; Wang, Fen; Yu, Songjie; Li, Xingwei
刊名	ADVANCED SYNTHESIS & CATALYSIS
	2016-03-17
卷号	358 期号:6 页码:880-886
关键词	Carbocyclization C-h Activation Alpha-diazo Esters Iridium(Iii) And Rhodium(Iii) Catalysis 2-phenylimidazo[1 2-a]Pyridines
ISSN号	1615-4150
DOI	10.1002/adsc.201500709
文献子类	Article
英文摘要	Iridium(III) and rhodium(III) complexes can catalyze the carbocyclization between 2-phenylimidazo[1,2-a]pyridine and alpha-diazo esters. The reaction occurs via C-H activation and dialkylation of the arene followed by intramolecular nucleophilic substitution. Iridium(III) and rhodium(III) catalysis offer complementary scopes with respect to the alpha-diazo esters.
WOS关键词	C-H BOND ; RH(III)-CATALYZED OXIDATIVE ANNULATION ; CARBENE MIGRATORY INSERTION ; N BOND ; CHELATION-ASSISTANCE ; INTERNAL ALKYNES ; NATURAL-PRODUCTS ; DIRECT ARYLATION ; DIRECTING GROUP ; ACTIVATION
WOS研究方向	Chemistry
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000373159200005
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170682]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Xingwei
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Li, Yunyun,Wang, Fen,Yu, Songjie,et al. Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(6):880-886.
APA	Li, Yunyun,Wang, Fen,Yu, Songjie,&Li, Xingwei.(2016).Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters.ADVANCED SYNTHESIS & CATALYSIS,358(6),880-886.
MLA	Li, Yunyun,et al."Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and alpha-Diazo Esters".ADVANCED SYNTHESIS & CATALYSIS 358.6(2016):880-886.