An artificial photosynthetic system containing an inorganic semiconductor and a molecular catalyst for photocatalytic water oxidation | |
Ye, Sheng1,2; Chen, Ruotian2; Xu, Yuxing2; Fan, Fengtao2; Du, Pingwu1; Zhang, Fuxiang2; Zong, Xu2; Chen, Tao2; Qi, Yu2; Chen, Ping2 | |
刊名 | JOURNAL OF CATALYSIS
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2016-06-01 | |
卷号 | 338页码:168-173 |
关键词 | Artificial Photosynthesis Water Oxidation Surface Photovoltage |
ISSN号 | 0021-9517 |
DOI | 10.1016/j.jcat.2016.02.024 |
文献子类 | Article |
英文摘要 | Water oxidation has long been considered to be the bottleneck of the water splitting reaction. Most semiconductor-based photocatalysts show low oxidation activity, mainly because of poor charge separation and transfer. Here, we construct an artificial photosynthetic system for photocatalytic water oxidation using BiVO4 as a photosensitizer and cubic Co complex as the oxygen-evolving catalyst. This system exhibits a high turnover frequency (TOF = 2.0 s(-1)) for O-2 evolution in the presence of NalO(3) as an electron acceptor, with an apparent quantum efficiency (AQE) yield of 4.5% at 420 nm, which is ninefold that of bare BiVO4 (0.5%), but the decomposition of the Co complex leads to decreased photocatalytic activity as time goes on. Spectroscopic studies confirmed an efficient interfacial hole transfer process from the semiconductor to the molecular catalyst. These results may shed light on designing artificial photocatalysts with highly efficient molecular catalysts and suitable semiconductor materials for water oxidation. (C) 2016 Elsevier Inc. All rights reserved. |
WOS关键词 | PHOTOSYSTEM-II ; LIGHT ; HYBRID ; INTERMEDIATE ; NANOCRYSTALS ; COCATALYSTS ; STABILITY ; COMPLEXES ; ANALOG |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
WOS记录号 | WOS:000376695500017 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170584] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Li, Can |
作者单位 | 1.Univ Sci & Technol China, Sch Chem & Mat Sci, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Ye, Sheng,Chen, Ruotian,Xu, Yuxing,et al. An artificial photosynthetic system containing an inorganic semiconductor and a molecular catalyst for photocatalytic water oxidation[J]. JOURNAL OF CATALYSIS,2016,338:168-173. |
APA | Ye, Sheng.,Chen, Ruotian.,Xu, Yuxing.,Fan, Fengtao.,Du, Pingwu.,...&Li, Can.(2016).An artificial photosynthetic system containing an inorganic semiconductor and a molecular catalyst for photocatalytic water oxidation.JOURNAL OF CATALYSIS,338,168-173. |
MLA | Ye, Sheng,et al."An artificial photosynthetic system containing an inorganic semiconductor and a molecular catalyst for photocatalytic water oxidation".JOURNAL OF CATALYSIS 338(2016):168-173. |
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