Vacuum ultraviolet photodissociation of hydrogen bromide

doi:10.1039/c6cp01956k

	Vacuum ultraviolet photodissociation of hydrogen bromide
	Su, Shu 2,3; Dorenkamp, Yvonne 1,4; Yu, Shengrui 2; Wodtke, Alec M.1,4; Dai, Dongxu 2; Yuan, Kaijun 2; Yang, Xueming 2
刊名	PHYSICAL CHEMISTRY CHEMICAL PHYSICS
	2016-06-14
卷号	18 期号:22 页码:15399-15405
ISSN号	1463-9076
DOI	10.1039/c6cp01956k
文献子类	Article
英文摘要	Photodissociation dynamics of HBr at a series of photolysis wavelengths in the range of 123.90-125.90 nm and at around 137.0 nm have been studied using the H atom Rydberg "tagging'' time-of-flight technique. The branching fractions between the channels forming ground Br(P-2(3/2)) and spin-orbit excited Br(P-2(1/2)) atoms together with the angular distributions of the products corresponding to these two channels have been measured. The photolysis wavelengths in this work excited the HBr molecule from the ground state X (1)Sigma(+) to various Rydberg states and the V (1)Sigma(+) ion-pair valence state. Predissociation via these states displays rich behavior, indicating the influence of the nature of initially excited states and the coupling to other bound or repulsive states on the predissociation dynamics.
WOS关键词	ENHANCED MULTIPHOTON IONIZATION ; ALIGNED DOPPLER SPECTROSCOPY ; ELECTRONIC-SPECTRA ; UV PHOTODISSOCIATION ; INTERSTELLAR CLOUDS ; HBR ; DYNAMICS ; HCL ; HALIDES ; STATES
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000378273500074
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170518]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yuan, Kaijun; Yang, Xueming
作者单位	1.Univ Gottingen, Inst Phys Chem, Tammannstr 6, Gottingen, Germany 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Max Planck Inst Biophys Chem, D-37077 Gottingen, Germany
推荐引用方式 GB/T 7714	Su, Shu,Dorenkamp, Yvonne,Yu, Shengrui,et al. Vacuum ultraviolet photodissociation of hydrogen bromide[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2016,18(22):15399-15405.
APA	Su, Shu.,Dorenkamp, Yvonne.,Yu, Shengrui.,Wodtke, Alec M..,Dai, Dongxu.,...&Yang, Xueming.(2016).Vacuum ultraviolet photodissociation of hydrogen bromide.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,18(22),15399-15405.
MLA	Su, Shu,et al."Vacuum ultraviolet photodissociation of hydrogen bromide".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 18.22(2016):15399-15405.