Cobalt(III)-Catalyzed C-C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C-H Activation | |
Kong, Lingheng1,2; Yu, Songjie2; Tang, Guodong2; Wang, He2; Zhou, Xukai1,2; Li, Xingwei2 | |
刊名 | ORGANIC LETTERS |
2016-08-05 | |
卷号 | 18期号:15页码:3802-3805 |
ISSN号 | 1523-7060 |
DOI | 10.1021/acs.orglett.6b01806 |
文献子类 | Article |
英文摘要 | Co(III)-catalyzed mild C-C couplings of arenes with strained rings such as 7-oxabenzonorbomadienes and 2-vinyloxirane have been realized. The transformation is proposed to undergo ortho C-H activation, olefin insertion, and subsequent beta-oxygen elimination. A broad range of synthetically useful functional groups are compatible, thus providing a new entry to access diversely 2-functionalized indoles. |
WOS关键词 | N-TYPE REACTIONS ; ALLYLIC ALCOHOLS ; BOND ACTIVATION ; MULTISUBSTITUTED ISOQUINOLINES ; INTERNAL ALKYNES ; INDOLE SYNTHESIS ; ALLYLATION ; FUNCTIONALIZATION ; AMIDATION ; ACCESS |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000381236300074 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170302] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Li, Xingwei |
作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Kong, Lingheng,Yu, Songjie,Tang, Guodong,et al. Cobalt(III)-Catalyzed C-C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C-H Activation[J]. ORGANIC LETTERS,2016,18(15):3802-3805. |
APA | Kong, Lingheng,Yu, Songjie,Tang, Guodong,Wang, He,Zhou, Xukai,&Li, Xingwei.(2016).Cobalt(III)-Catalyzed C-C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C-H Activation.ORGANIC LETTERS,18(15),3802-3805. |
MLA | Kong, Lingheng,et al."Cobalt(III)-Catalyzed C-C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C-H Activation".ORGANIC LETTERS 18.15(2016):3802-3805. |
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