Catalytic oxidative C-C bond cleavage route of levulinic acid and methyl levulinate

doi:10.1039/c6ra16149a

	Catalytic oxidative C-C bond cleavage route of levulinic acid and methyl levulinate
	Ma, Yangyang 1,2; Xia, Fei 1,2; Du, Zhongtian 3; Liu, Junxia 2; Xu, Jie 2
刊名	RSC ADVANCES
	2016
卷号	6 期号:76 页码:72744-72749
ISSN号	2046-2069
DOI	10.1039/c6ra16149a
文献子类	Article
英文摘要	Recently, obtaining value-added chemicals from biomass resources has attracted considerable attention. Levulinic acid is one of the most important biomass platform compounds, which could be obtained from carbohydrate biomass. In this work, levulinic acid was selectively converted into C4 product, including succinic anhydride, via catalytic oxidation with a manganese catalyst in acetic anhydride. Moreover, an unexpected product of maleic anhydride was obtained, which greatly differs from that of levulinate ester. The pathway for formation of maleic anhydride was studied by monitoring and confirming intermediates alpha-angelica lactone and its derivative 2-methyl-5-oxotetrahydro-2-furanyl acetate. Based on the obtained mechanistic information, the different behaviour between the oxidative cleavage of levulinic acid and levulinate ester was further discussed.
WOS关键词	MALEIC-ANHYDRIDE ; SUCCINIC ANHYDRIDE ; SELECTIVE HYDROGENATION ; PHASE HYDROGENATION ; RENEWABLE RESOURCES ; NICKEL-CATALYSTS ; LIQUID-PHASE ; N-BUTANE ; BIOMASS ; CONVERSION
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000381513300110
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170196]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Xu, Jie
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian, Peoples R China 3.Dalian Univ Technol, Sch Petr & Chem Engn, Panjin 124221, Peoples R China
推荐引用方式 GB/T 7714	Ma, Yangyang,Xia, Fei,Du, Zhongtian,et al. Catalytic oxidative C-C bond cleavage route of levulinic acid and methyl levulinate[J]. RSC ADVANCES,2016,6(76):72744-72749.
APA	Ma, Yangyang,Xia, Fei,Du, Zhongtian,Liu, Junxia,&Xu, Jie.(2016).Catalytic oxidative C-C bond cleavage route of levulinic acid and methyl levulinate.RSC ADVANCES,6(76),72744-72749.
MLA	Ma, Yangyang,et al."Catalytic oxidative C-C bond cleavage route of levulinic acid and methyl levulinate".RSC ADVANCES 6.76(2016):72744-72749.