Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst

doi:10.1016/S1872-2067(16)62503-2

	Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst
	Ren, Lanhui 1,2; Wang, Lianyue 2; Lu, Ying 2; Li, Guosong 2; Gao, Shuang 2
刊名	CHINESE JOURNAL OF CATALYSIS
	2016-08-01
卷号	37 期号:8 页码:1216-1221
关键词	Oxidation Heterogeneous Catalyst Ketone C-h Bond Manganese
ISSN号	0253-9837
DOI	10.1016/S1872-2067(16)62503-2
文献子类	Article
英文摘要	Novel reusable MnO,-N@C catalyst has been developed for the direct oxidation of N-heterocycles under solvent-free conditions using TBHP as benign oxidant to give the corresponding N-heterocyclic ketones. The catalytic system exhibited a broad substrate scope and excellent regioselectivity, as well as being amenable to gram-scale synthesis. This MnOx-N@C catalyst also showed good reusability and was successfully recycled six times without any significant loss of activity. (C) 2016, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词	SELECTIVE OXIDATION ; MOLECULAR-OXYGEN ; BENZYLPYRIDINES ; ALCOHOLS
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000381326900004
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170130]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Gao, Shuang
作者单位	1.Dalian Univ Technol, Coll Chem, Dalian 116024, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
推荐引用方式 GB/T 7714	Ren, Lanhui,Wang, Lianyue,Lu, Ying,et al. Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst[J]. CHINESE JOURNAL OF CATALYSIS,2016,37(8):1216-1221.
APA	Ren, Lanhui,Wang, Lianyue,Lu, Ying,Li, Guosong,&Gao, Shuang.(2016).Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst.CHINESE JOURNAL OF CATALYSIS,37(8),1216-1221.
MLA	Ren, Lanhui,et al."Direct oxidation of the C-sp3-H bonds of N-heterocyclic compounds to give the corresponding ketones using a reusable heterogeneous MnOx-N@C catalyst".CHINESE JOURNAL OF CATALYSIS 37.8(2016):1216-1221.