One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates

doi:10.1039/c6qo00141f

	One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates
	Wu, Chaoqiang 1; Wu, Guojiao 1; Zhang, Yan 1; Wang, Jianbo 1,2
刊名	ORGANIC CHEMISTRY FRONTIERS
	2016
卷号	3 期号:7 页码:817-822
ISSN号	2052-4129
DOI	10.1039/c6qo00141f
文献子类	Article
英文摘要	A transition-metal-free method for the synthesis of benzylic boronate esters with arylboronic acids and trimethylsilyldiazomethane (TMSCHN2) has been developed. This transformation is a straightforward homologation of arylboronic acids, which represents a unique approach toward the preparation of pinacol benzylboronates. The reaction has a wide substrate scope and good functional-group tolerance, and it can be scaled up easily.
WOS关键词	IRIDIUM-CATALYZED BORYLATION ; CROSS-COUPLING REACTIONS ; C-H BONDS ; BENZYL HALIDES ; ALKENYLBORONIC ACIDS ; ALKYLBORON COMPOUNDS ; ESTERS ; METAL ; ORGANOBORANES ; BIS(PINACOLATO)DIBORON
WOS研究方向	Chemistry
语种	英语
出版者	CHINESE CHEMICAL SOC
WOS记录号	WOS:000382496400006
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/170066]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wang, Jianbo
作者单位	1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,et al. One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(7):817-822.
APA	Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,&Wang, Jianbo.(2016).One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates.ORGANIC CHEMISTRY FRONTIERS,3(7),817-822.
MLA	Wu, Chaoqiang,et al."One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates".ORGANIC CHEMISTRY FRONTIERS 3.7(2016):817-822.