One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates | |
Wu, Chaoqiang1; Wu, Guojiao1; Zhang, Yan1; Wang, Jianbo1,2 | |
刊名 | ORGANIC CHEMISTRY FRONTIERS
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2016 | |
卷号 | 3期号:7页码:817-822 |
ISSN号 | 2052-4129 |
DOI | 10.1039/c6qo00141f |
文献子类 | Article |
英文摘要 | A transition-metal-free method for the synthesis of benzylic boronate esters with arylboronic acids and trimethylsilyldiazomethane (TMSCHN2) has been developed. This transformation is a straightforward homologation of arylboronic acids, which represents a unique approach toward the preparation of pinacol benzylboronates. The reaction has a wide substrate scope and good functional-group tolerance, and it can be scaled up easily. |
WOS关键词 | IRIDIUM-CATALYZED BORYLATION ; CROSS-COUPLING REACTIONS ; C-H BONDS ; BENZYL HALIDES ; ALKENYLBORONIC ACIDS ; ALKYLBORON COMPOUNDS ; ESTERS ; METAL ; ORGANOBORANES ; BIS(PINACOLATO)DIBORON |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | CHINESE CHEMICAL SOC |
WOS记录号 | WOS:000382496400006 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/170066] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Wang, Jianbo |
作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,et al. One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates[J]. ORGANIC CHEMISTRY FRONTIERS,2016,3(7):817-822. |
APA | Wu, Chaoqiang,Wu, Guojiao,Zhang, Yan,&Wang, Jianbo.(2016).One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates.ORGANIC CHEMISTRY FRONTIERS,3(7),817-822. |
MLA | Wu, Chaoqiang,et al."One-carbon homologation of arylboronic acids: a convenient approach to the synthesis of pinacol benzylboronates".ORGANIC CHEMISTRY FRONTIERS 3.7(2016):817-822. |
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