Synthesis of High-Density Aviation Fuel with Cyclopentanol

doi:10.1021/acssuschemeng.6b01678

	Synthesis of High-Density Aviation Fuel with Cyclopentanol
	Wang, Xiaodong 2; Hu, Yancheng 2; Wang, Wentao 2; Wang, Aiqin 1,2; Chen, Fang 2,3; Li, Ning 1,2; Cong, Yu 2; Yang, Xiaofeng 2; Zhang, Tao 1,2; Li, Lin 2
刊名	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
	2016-11-01
卷号	4 期号:11 页码:6160-6166
关键词	Jet Fuel Lignocellulose Cyclopentanol Dehydration Oligomerization/rearrangement Solid Acid Catalyst
ISSN号	2168-0485
DOI	10.1021/acssuschemeng.6b01678
文献子类	Article
英文摘要	Decalin is the main component of JP-900, a thermally stable and high-energy density jet fuel. Decalin is also an important component of advanced jet fuels. Cyclopentanol is a platform compound that can be derived from lignocellulose. In this work, a mixture of C-10 and C-15 polycycloalkanes (with decalin as the major component) was first synthesized by the oligomerization/rearrangement of cyclopentene from the dehydration of cyclopentanol, followed by hydrogenation. Among the investigated catalysts, Amberlyst-36 resin demonstrated the highest activity and excellent stability for cyclopentanol dehydration and cyclopentene oligomerization/rearrangement. The influences of reaction temperature and reaction time on the catalytic performances of Amberlyst-36 resin for both reactions were investigated. Under the optimum conditions, 84.0% carbon yield of cyclopentene was obtained from cyclopentanol dehydration, and 74.2% carbon yield of C-10 and C-15 polycycloalkenes was achieved by the oligomerization/rearrangement of cyclopentene. Finally, the C-10 and C-15 polycycloalkenes from the oligomerization/rearrangement of cyclopentene were further hydrogenated to a mixture of C-10 and C-15 polycycloalkanes with decalin as the major component (77% selectivity). This polycycloalkane mixture has high density (0.896 g mL(-1)). As a potential application, it can be used as an additive to improve the volumetric calorific values of conventional biojet fuels.
WOS关键词	AROMATIC-HYDROCARBONS ; TRANSPORTATION FUELS ; CATALYTIC CONVERSION ; GAMMA-VALEROLACTONE ; PLATFORM MOLECULES ; LIQUID ALKANES ; JET-FUEL ; BIOMASS ; ACID ; LIGNOCELLULOSE
WOS研究方向	Chemistry ; Engineering
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000387428700042
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169790]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Li, Ning; Zhang, Tao
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Collaborat Innovat Ctr Chem Energy Mat iChEM, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Xiaodong,Hu, Yancheng,Wang, Wentao,et al. Synthesis of High-Density Aviation Fuel with Cyclopentanol[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2016,4(11):6160-6166.
APA	Wang, Xiaodong.,Hu, Yancheng.,Wang, Wentao.,Wang, Aiqin.,Chen, Fang.,...&Li, Shanshan.(2016).Synthesis of High-Density Aviation Fuel with Cyclopentanol.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,4(11),6160-6166.
MLA	Wang, Xiaodong,et al."Synthesis of High-Density Aviation Fuel with Cyclopentanol".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 4.11(2016):6160-6166.