A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties

doi:10.1039/c6ce01827k

	A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties
	Jiang, Heqing 2; Jiao, Chengli 2; Jiang, Xia 1; Chu, Hailiang 3; Sun, Lixian 3
刊名	CRYSTENGCOMM
	2016
卷号	18 期号:44 页码:8683-8687
ISSN号	1466-8033
DOI	10.1039/c6ce01827k
文献子类	Article
英文摘要	A novel 3D mixed-valent Cu-I/Cu-II metal-organic framework has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, photoluminescence spectroscopy, thermal gravimetric analysis, and powder X-ray diffraction. The structure possesses a 3D open framework constructed from the linkages of 1D [Cu-I(4,4'-bipy)](n) chains with [Cu-II(oda)(2)](2-) cationic subunits. The chemical sensing properties of this MOF have been studied by the quartz crystal microbalance technique. The framework exhibits good selectivity and sensitivity to water with respect to other organic solvents in view of chemical sensing applications.
WOS关键词	COORDINATION POLYMER ; SOLVENT MOLECULES ; LIGAND ; LUMINESCENCE ; COMPLEXES ; CATALYSTS ; SORPTION ; SENSORS ; BINDING ; METHANE
WOS研究方向	Chemistry ; Crystallography
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000387975900018
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169730]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Jiang, Heqing; Sun, Lixian
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, 189 Songling Rd, Qingdao 266101, Peoples R China 3.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China
推荐引用方式 GB/T 7714	Jiang, Heqing,Jiao, Chengli,Jiang, Xia,et al. A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties[J]. CRYSTENGCOMM,2016,18(44):8683-8687.
APA	Jiang, Heqing,Jiao, Chengli,Jiang, Xia,Chu, Hailiang,&Sun, Lixian.(2016).A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties.CRYSTENGCOMM,18(44),8683-8687.
MLA	Jiang, Heqing,et al."A mixed-valent Cu-I/Cu-II metal-organic framework with selective chemical sensing properties".CRYSTENGCOMM 18.44(2016):8683-8687.