Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions

doi:10.1039/c6gc02868c

	Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions
	Zheng, Mingyuan 2; Sun, Ruiyan 1,2; Li, Xinsheng 1,2; Pang, Jifeng 2; Wang, Aiqin 2; Wang, Xiaodong 2; Zhang, Tao 2
刊名	GREEN CHEMISTRY
	2017
卷号	19 期号:3 页码:638-642
ISSN号	1463-9262
DOI	10.1039/c6gc02868c
文献子类	Article
英文摘要	A two-step synthetic approach for the production of renewable 1,3-pentadiene was reported: xylitol deoxydehydration (DODH) by formic acid to 2,4-pentadien-1-ol, 1-formate (2E), followed by deoxygenation to 1,3-pentadiene over Pd/C. The overall carbon yield of 1,3-pentadiene reached 51.8% under the optimized conditions.
WOS关键词	ETHYLENE-GLYCOL ; BIOMASS ; CONVERSION ; OLEFINS ; DEHYDRATION ; CHEMICALS ; DECARBONYLATION ; ALCOHOLS ; PENTITOLS ; REAGENT
WOS研究方向	Chemistry
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000395630000008
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169486]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zheng, Mingyuan; Zhang, Tao
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Zheng, Mingyuan,Sun, Ruiyan,Li, Xinsheng,et al. Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions[J]. GREEN CHEMISTRY,2017,19(3):638-642.
APA	Zheng, Mingyuan.,Sun, Ruiyan.,Li, Xinsheng.,Pang, Jifeng.,Wang, Aiqin.,...&Zhang, Tao.(2017).Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions.GREEN CHEMISTRY,19(3),638-642.
MLA	Zheng, Mingyuan,et al."Production of renewable 1,3-pentadiene from xylitol via formic acid-mediated deoxydehydration and palladium-catalyzed deoxygenation reactions".GREEN CHEMISTRY 19.3(2017):638-642.