An accidental resonance mediated predissociation pathway of water molecules excited to the electronic (C)over-tilde state

doi:10.1039/c7cp06286a

	An accidental resonance mediated predissociation pathway of water molecules excited to the electronic (C)over-tilde state
	Wu, Guorong 1,3; Yang, Dongyuan 1,2; Yuan, Kaijun 1; Dai, Dongxu 1,3; Yang, Xueming 1,3; He, Zhigang 1; Chen, Zhichao 1
刊名	PHYSICAL CHEMISTRY CHEMICAL PHYSICS
	2017-11-28
卷号	19 期号:44 页码:29795-29800
ISSN号	1463-9076
DOI	10.1039/c7cp06286a
文献子类	Article
英文摘要	The predissociation dynamics of water molecules in the electronic (C) over tilde state were studied using the time-resolved photoelectron imaging method. Both vibrationless and vibrationally excited states in the (C) over tilde electronic state were studied, with an emphasis on the vibrational excitation effects on the predissociation dynamics of the (C) over tilde state. Besides the well-known rotationally and non-rotationally mediated predissociation pathways (Proc. Natl. Acad. Sci. U. S. A., 2008, 105, 19148), an accidental resonance mediated predissociation pathway for the first bending mode excited state in the (C) over tilde electronic state of H2O is revealed, providing an excellent example of competition between non-adiabatic decay pathways involving at least five electronic states.
WOS关键词	MULTIPHOTON IONIZATION SPECTROSCOPY ; OH PROMPT EMISSION ; VACUUM-ULTRAVIOLET ; (D)OVER-TILDE STATES ; 2 COMETS ; H2O ; D2O ; DYNAMICS ; PHOTODISSOCIATION ; (B)OVER-TILDE
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000415576800008
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/169264]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Wu, Guorong; Yang, Xueming
作者单位	1.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Univ Sci & Technol China, Synerget Innovat Ctr Quantum Informat & Quantum P, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Wu, Guorong,Yang, Dongyuan,Yuan, Kaijun,et al. An accidental resonance mediated predissociation pathway of water molecules excited to the electronic (C)over-tilde state[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2017,19(44):29795-29800.
APA	Wu, Guorong.,Yang, Dongyuan.,Yuan, Kaijun.,Dai, Dongxu.,Yang, Xueming.,...&Chen, Zhichao.(2017).An accidental resonance mediated predissociation pathway of water molecules excited to the electronic (C)over-tilde state.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19(44),29795-29800.
MLA	Wu, Guorong,et al."An accidental resonance mediated predissociation pathway of water molecules excited to the electronic (C)over-tilde state".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19.44(2017):29795-29800.