Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand

doi:10.1021/acs.organomet.7b00902

	Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand
	Wang, Qingfu 1,2; Chai, Huining 1,2; Yu, Zhengkun 2,3
刊名	ORGANOMETALLICS
	2018-02-26
卷号	37 期号:4 页码:584-591
ISSN号	0276-7333
DOI	10.1021/acs.organomet.7b00902
文献子类	Article
英文摘要	Ruthenium(II) hydride complexes bearing a pyrazolyl-(2-indol-1-yl)-pyridine ligand were synthesized and structurally characterized by NMR analysis and X-ray single crystal crystallographic determinations. These complexes efficiently catalyzed acceptorless dehydrogenation of N-heterocycles and secondary alcohols, respectively, exhibiting highly catalytic activity with a broad substrate scope. The present work has established a strategy to construct highly active transition metal complex catalysts and provides an atom-economical and environmentally benign protocol for the synthesis of aromatic N-heterocydic compounds and ketones.
WOS关键词	ASYMMETRIC TRANSFER HYDROGENATION ; TETRAHYDRO-BETA-CARBOLINES ; CATALYSTS BEARING ; REVERSIBLE DEHYDROGENATION ; IMIDAZOLYL LIGAND ; NITROGEN-HETEROCYCLES ; ARYL CHLORIDES ; NNN LIGAND ; KETONES ; OXIDATION
WOS研究方向	Chemistry
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000426618800011
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168870]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Yu, Zhengkun
作者单位	1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, 457 Zhongshan Rd, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 354 Fenglin Rd, Shanghai 200032, Peoples R China
推荐引用方式 GB/T 7714	Wang, Qingfu,Chai, Huining,Yu, Zhengkun. Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand[J]. ORGANOMETALLICS,2018,37(4):584-591.
APA	Wang, Qingfu,Chai, Huining,&Yu, Zhengkun.(2018).Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand.ORGANOMETALLICS,37(4),584-591.
MLA	Wang, Qingfu,et al."Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-indolyl-pyridine Ligand".ORGANOMETALLICS 37.4(2018):584-591.