Integrating Perovskite Photovoltaics and Noble-Metal-Free Catalysts toward Efficient Solar Energy Conversion and H2S Splitting | |
Ma, Weiguang; Han, Jingfeng; Yu, Wei; Yang, Dong; Wang, Hong; Zong, Xu; Li, Can | |
刊名 | ACS CATALYSIS |
2016-09-01 | |
卷号 | 6期号:9页码:6198-6206 |
关键词 | Perovskite Photovoltaics Noble-metal-free Catalysts Redox Mediators Solar Energy Conversion H2s Splitting |
ISSN号 | 2155-5435 |
DOI | 10.1021/acscatal.6b01772 |
文献子类 | Article |
英文摘要 | Hydrogen sulfide (H2S) has been considered as a potential hydrogen source. Identifying efficient solar-driven processes and low-cost materials that can extract hydrogen from H2S is highly attractive. Herein, for the first time, we reported the establishment of a perovskite photovoltaic-electrolysis (PV-EC) H2S splitting system by integrating a single perovskite solar cell, noble-metal-free catalysts, and H2S splitting reaction with the aid of mediators. The as-established system delivered a solar-to-chemical energy conversion efficiency of up to 13.5% during the PV-EC step by using molybdenum-tungsten phosphide (Mo-W-P) as the catalyst for a hydrogen evolution reaction (HER) and a graphite carbon sheet as the catalyst for the oxidation of mediators, respectively. To the best of our knowledge, this is among the highest value ever reported for the artificial conversion of solar to chemical energy using perovskite solar cells. Moreover, upon integration with the PV-EC system, a H2S splitting reaction with a net energy conversion efficiency of 3.5% can be accomplished, and the overall energy consumption to obtain an equivalent amount of H-2 from H2S is reduced by ca. 43.3% compared with that from water splitting. This paradigm of producing value-added chemicals by consuming negative value waste products is solely based on low-cost materials and a simpler system configuration, which significantly improves the economic sustainability of the process. |
WOS关键词 | HYDROGEN EVOLUTION ; SULFUR RECOVERY ; CELLS ; ELECTROCATALYST ; GENERATION ; SULFIDE ; DRIVEN ; PHOTOELECTROLYSIS ; NANOPARTICLES ; PHOTOCATALYST |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000382714000064 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168300] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Zong, Xu; Li, Can |
作者单位 | Chinese Acad Sci, Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian Natl Lab Clean Energy, State Key Lab Catalysis,Dalian Inst Chem Phys, Zhongshan Rd 457, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Weiguang,Han, Jingfeng,Yu, Wei,et al. Integrating Perovskite Photovoltaics and Noble-Metal-Free Catalysts toward Efficient Solar Energy Conversion and H2S Splitting[J]. ACS CATALYSIS,2016,6(9):6198-6206. |
APA | Ma, Weiguang.,Han, Jingfeng.,Yu, Wei.,Yang, Dong.,Wang, Hong.,...&Li, Can.(2016).Integrating Perovskite Photovoltaics and Noble-Metal-Free Catalysts toward Efficient Solar Energy Conversion and H2S Splitting.ACS CATALYSIS,6(9),6198-6206. |
MLA | Ma, Weiguang,et al."Integrating Perovskite Photovoltaics and Noble-Metal-Free Catalysts toward Efficient Solar Energy Conversion and H2S Splitting".ACS CATALYSIS 6.9(2016):6198-6206. |
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