Rotational alignment of products from the NOCl+Ca chemiluminescent reaction

	Rotational alignment of products from the NOCl+Ca chemiluminescent reaction
	Zhan, JP; Yang, HP; Han, KL; Deng, WQ; He, GZ; Lou, NQ
刊名	JOURNAL OF PHYSICAL CHEMISTRY A
	1997-10-09
卷号	101 期号:41 页码:7486-7489
ISSN号	1089-5639
文献子类	Article
英文摘要	The product rotational alignment [P-2((J) over cap'.(k) over cap)] = -0.35 +/- 0.04, -0.15 +/- 0.02 for CaCl(B), CaCl(A) are obtained from Ca + NOCl chemiluminescent reactions, respectively. The experiments are carried out under single collision conditions in a beam-gas apparatus. Quasi-classical trajectory (QCT) calculations for Ca + NOCl reaction have been carried out. The calculated results agree well with the experimental ones. The strong product alignments for the reactions are attributed to attractive potential surfaces. It is plausible that the difference of the rotational alignment between the A(2) Pi and B-2 Sigma states of the products is due to their different potential energy surfaces (PESs).
WOS关键词	ANGULAR-MOMENTUM ; EXCHANGE-REACTIONS ; ORIENTATION ; PHOTODISSOCIATION ; POLARIZATION ; DEPENDENCE ; MAGNITUDE ; VELOCITY ; SPECTRA
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:A1997YA48400005
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/168238]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	CHINESE ACAD SCI,DALIAN INST CHEM PHYS,STATE KEY LAB MOL REACT DYNAM,DALIAN 116023,PEOPLES R CHINA
推荐引用方式 GB/T 7714	Zhan, JP,Yang, HP,Han, KL,et al. Rotational alignment of products from the NOCl+Ca chemiluminescent reaction[J]. JOURNAL OF PHYSICAL CHEMISTRY A,1997,101(41):7486-7489.
APA	Zhan, JP,Yang, HP,Han, KL,Deng, WQ,He, GZ,&Lou, NQ.(1997).Rotational alignment of products from the NOCl+Ca chemiluminescent reaction.JOURNAL OF PHYSICAL CHEMISTRY A,101(41),7486-7489.
MLA	Zhan, JP,et al."Rotational alignment of products from the NOCl+Ca chemiluminescent reaction".JOURNAL OF PHYSICAL CHEMISTRY A 101.41(1997):7486-7489.