HIGHLY-ACTIVE ALKALI-METAL HYDRIDES - THEIR CATALYTIC SYNTHESES AND PROPERTIES | |
ZHANG, YP; LIAO, SJ; XU, Y | |
刊名 | JOURNAL OF MOLECULAR CATALYSIS
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1993-10-25 | |
卷号 | 84期号:3页码:211-221 |
关键词 | Alkali Metal Hydrides Alkali Metal Naphthalenes Hydrogenation Titanium Catalyst |
ISSN号 | 0304-5102 |
文献子类 | Article |
英文摘要 | Highly active alkali metal hydrides (M = Li, Na and K) can be prepared easily by the direct hydrogenation of alkali metals catalyzed by TiCl4 and naphthalene under mild conditions. The reaction scheme of this catalytic reaction is discussed. The hydrides obtained are in the form of a highly dispersed powder with an average primary particle size around 20 nm. The synthetic utility of these hydrides has been explored. Two of the examples are described. |
WOS关键词 | COMPLEX REDUCING AGENTS ; SODIUM HYDRIDE ; HYDROGENATION CATALYSTS ; ORGANIC-SYNTHESIS ; MILD CONDITIONS ; ACTIVATION ; REDUCTION ; MAGNESIUM ; MECHANISM ; REAGENTS |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:A1993MF49900001 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167738] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | CHINESE ACAD SCI,DALIAN INST CHEM PHYS,POB 110,DALIAN,PEOPLES R CHINA |
推荐引用方式 GB/T 7714 | ZHANG, YP,LIAO, SJ,XU, Y. HIGHLY-ACTIVE ALKALI-METAL HYDRIDES - THEIR CATALYTIC SYNTHESES AND PROPERTIES[J]. JOURNAL OF MOLECULAR CATALYSIS,1993,84(3):211-221. |
APA | ZHANG, YP,LIAO, SJ,&XU, Y.(1993).HIGHLY-ACTIVE ALKALI-METAL HYDRIDES - THEIR CATALYTIC SYNTHESES AND PROPERTIES.JOURNAL OF MOLECULAR CATALYSIS,84(3),211-221. |
MLA | ZHANG, YP,et al."HIGHLY-ACTIVE ALKALI-METAL HYDRIDES - THEIR CATALYTIC SYNTHESES AND PROPERTIES".JOURNAL OF MOLECULAR CATALYSIS 84.3(1993):211-221. |
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