THE PRODUCT POLARIZATION OF CHEMILUMINESCENT REACTIONS OF ORBITAL ALIGNED CA(1P1) WITH CH3I AND C2H5I

	THE PRODUCT POLARIZATION OF CHEMILUMINESCENT REACTIONS OF ORBITAL ALIGNED CA(1P1) WITH CH3I AND C2H5I
	DING, GW; YANG, WS; SUN, WZ; XU, DL; HE, GZ; LOU, NQ
刊名	CHEMICAL PHYSICS LETTERS
	1994-03-25
卷号	220 期号:1-2 页码:1-6
ISSN号	0009-2614
文献子类	Article
英文摘要	The product polarization in the beam-gas chemiluminescent reactions Ca(P-1(1)) + RI --> CaI* + R for different initial Ca electronic orbital alignments are both probed experimentally and calculated with the DIP extension of the DIPR model (the direct interaction with product repulsion (DIPR) model, with product repulsion distributed as in photodissociation (DIP) model). The experimental results show that the product rotational alignment is independent of the Ca(P-1(1)) orbital alignment and that the distribution of the product rotational vector becomes less anisotropic as the number of carbon atoms in R increased. The reagent alignment sensitivity factors of the reaction Ca(P-1(1)) + CH3I --> CaI* + CH3 are also investigated.
WOS关键词	CHEMI-LUMINESCENT REACTIONS ; ANGULAR-MOMENTUM ; ALIGNMENT ; COLLISIONS ; MODEL
WOS研究方向	Chemistry ; Physics
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:A1994NC82400001
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167704]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	DING, GW
推荐引用方式 GB/T 7714	DING, GW,YANG, WS,SUN, WZ,et al. THE PRODUCT POLARIZATION OF CHEMILUMINESCENT REACTIONS OF ORBITAL ALIGNED CA(1P1) WITH CH3I AND C2H5I[J]. CHEMICAL PHYSICS LETTERS,1994,220(1-2):1-6.
APA	DING, GW,YANG, WS,SUN, WZ,XU, DL,HE, GZ,&LOU, NQ.(1994).THE PRODUCT POLARIZATION OF CHEMILUMINESCENT REACTIONS OF ORBITAL ALIGNED CA(1P1) WITH CH3I AND C2H5I.CHEMICAL PHYSICS LETTERS,220(1-2),1-6.
MLA	DING, GW,et al."THE PRODUCT POLARIZATION OF CHEMILUMINESCENT REACTIONS OF ORBITAL ALIGNED CA(1P1) WITH CH3I AND C2H5I".CHEMICAL PHYSICS LETTERS 220.1-2(1994):1-6.