Recent developments in copper-catalyzed reactions of diazo compounds
Zhao, Xia1; Zhang, Yan2; Wang, Jianbo2
刊名CHEMICAL COMMUNICATIONS
2012
卷号48期号:82页码:10162-10173
ISSN号1359-7345
DOI10.1039/c2cc34406h
文献子类Article
英文摘要Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates that undergo diverse transformations. In recent years, the selectivity and efficiency of these important conversions have been further improved. In particular, breakthroughs have been made in catalytic asymmetric polar X-H bond insertion reactions. Moreover, novel transformations based on copper carbene, namely copper-catalyzed cross-couplings of diazo compounds, have emerged as powerful methods for carbon-carbon bond formations. This feature article summarizes the most recent developments in this area.
WOS关键词H INSERTION REACTIONS ; HIGHLY ENANTIOSELECTIVE INSERTION ; ALPHA-DIAZOCARBONYL COMPOUNDS ; MEDIATED DIRECT ARYLATION ; ORGANIC-SYNTHESIS ; CYCLOPROPANATION REACTIONS ; 3-COMPONENT REACTION ; CARBENOID INSERTION ; TERMINAL ALKYNES ; SULFUR YLIDES
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000308929000002
内容类型期刊论文
源URL[http://cas-ir.dicp.ac.cn/handle/321008/167262]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Zhao, Xia
作者单位1.Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Coll Chem, Tianjin 300387, Peoples R China
2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Beijing 100871, Peoples R China
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GB/T 7714
Zhao, Xia,Zhang, Yan,Wang, Jianbo. Recent developments in copper-catalyzed reactions of diazo compounds[J]. CHEMICAL COMMUNICATIONS,2012,48(82):10162-10173.
APA Zhao, Xia,Zhang, Yan,&Wang, Jianbo.(2012).Recent developments in copper-catalyzed reactions of diazo compounds.CHEMICAL COMMUNICATIONS,48(82),10162-10173.
MLA Zhao, Xia,et al."Recent developments in copper-catalyzed reactions of diazo compounds".CHEMICAL COMMUNICATIONS 48.82(2012):10162-10173.
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