Recent developments in copper-catalyzed reactions of diazo compounds | |
Zhao, Xia1; Zhang, Yan2; Wang, Jianbo2 | |
刊名 | CHEMICAL COMMUNICATIONS
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2012 | |
卷号 | 48期号:82页码:10162-10173 |
ISSN号 | 1359-7345 |
DOI | 10.1039/c2cc34406h |
文献子类 | Article |
英文摘要 | Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates that undergo diverse transformations. In recent years, the selectivity and efficiency of these important conversions have been further improved. In particular, breakthroughs have been made in catalytic asymmetric polar X-H bond insertion reactions. Moreover, novel transformations based on copper carbene, namely copper-catalyzed cross-couplings of diazo compounds, have emerged as powerful methods for carbon-carbon bond formations. This feature article summarizes the most recent developments in this area. |
WOS关键词 | H INSERTION REACTIONS ; HIGHLY ENANTIOSELECTIVE INSERTION ; ALPHA-DIAZOCARBONYL COMPOUNDS ; MEDIATED DIRECT ARYLATION ; ORGANIC-SYNTHESIS ; CYCLOPROPANATION REACTIONS ; 3-COMPONENT REACTION ; CARBENOID INSERTION ; TERMINAL ALKYNES ; SULFUR YLIDES |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000308929000002 |
内容类型 | 期刊论文 |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167262] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Zhao, Xia |
作者单位 | 1.Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Coll Chem, Tianjin 300387, Peoples R China 2.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci,Minist Educ, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Xia,Zhang, Yan,Wang, Jianbo. Recent developments in copper-catalyzed reactions of diazo compounds[J]. CHEMICAL COMMUNICATIONS,2012,48(82):10162-10173. |
APA | Zhao, Xia,Zhang, Yan,&Wang, Jianbo.(2012).Recent developments in copper-catalyzed reactions of diazo compounds.CHEMICAL COMMUNICATIONS,48(82),10162-10173. |
MLA | Zhao, Xia,et al."Recent developments in copper-catalyzed reactions of diazo compounds".CHEMICAL COMMUNICATIONS 48.82(2012):10162-10173. |
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