Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor

doi:10.1039/c8gc00039e

	Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor
	Zhang, Tao 3; Liu, Fei 3; Liu, Qiaoyun 3,4; Xu, Jinming 3; Li, Lei 5; Cui, Yi-Tao 2; Lang, Rui 3; Li, Lin 3; Su, Yang 3; Miao, Shu 3
刊名	GREEN CHEMISTRY
	2018-04-21
卷号	20 期号:8 页码:1770-1776
ISSN号	1463-9262
DOI	10.1039/c8gc00039e
文献子类	Article
英文摘要	The synthesis of bio-based linear diols is the subject of many research studies. However, one of the main obstacles in industrial development is the difficulty in controlling product selectivity. Here, we report the catalytic conversion of furfural to 1,4-pentanediol (PD) in the presence of Ru supported on an ordered mesoporous carbon (CMK-3) under pressure of H-2 and CO2 in water. In contrast to previous catalytic pathways, this work is distinct in that it yields 1,4-PD as an exclusive product, instead of a mixture of 1,2-and 1,5-PD as usual. Under optimized conditions, 1,4-PD was obtained in 90% yield, and in a one-pot reaction, directly from furfural. We disclose that the conversion of furfural to 1,4-PD followed an unusual catalytic route. It implies a bifunctional catalytic pathway based on sequential catalytic hydrogenation reactions and an acid-catalyzed Piancatelli's rearrangement.
WOS关键词	LEVULINIC ACID ; GAMMA-VALEROLACTONE ; ETHYLENE-GLYCOL ; CHEMOSELECTIVE HYDROGENOLYSIS ; HYDROGENATION ; CHEMICALS ; BIOMASS ; OXIDATION ; CELLULOSE ; PLATFORM
WOS研究方向	Chemistry ; Science & Technology - Other Topics
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000430708900009
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/167184]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Qiao, Botao; Jerome, Francois; Wang, Aiqin
作者单位	1.Univ Poitiers, CNRS, Inst Chim Milieux & Mat Poitiers, F-86073 Poitiers, France 2.Univ Tokyo, Inst Solid State Phys, Tokyo, Hyogo 6795198, Japan 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Hyogo, Synchrotron Radiat Nanotechnol Ctr, Kobe, Hyogo 6795165, Japan
推荐引用方式 GB/T 7714	Zhang, Tao,Liu, Fei,Liu, Qiaoyun,et al. Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor[J]. GREEN CHEMISTRY,2018,20(8):1770-1776.
APA	Zhang, Tao.,Liu, Fei.,Liu, Qiaoyun.,Xu, Jinming.,Li, Lei.,...&Wang, Aiqin.(2018).Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor.GREEN CHEMISTRY,20(8),1770-1776.
MLA	Zhang, Tao,et al."Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor".GREEN CHEMISTRY 20.8(2018):1770-1776.