Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives

doi:10.1055/s-0037-1610220

	Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives
	Lou, Ning 1; Kraevaya, Olga A.4; Gan, Liangbing 1,2; Troshin, Pavel A.3,4
刊名	SYNTHESIS-STUTTGART
	2018-11-01
卷号	50 期号:21 页码:4283-4289
关键词	fullerene amination pyrrole substituent effect nucleophilic aromatic substitution
ISSN号	0039-7881
DOI	10.1055/s-0037-1610220
通讯作者	Troshin, Pavel A.(troshin2003@inbox.ru) ; Gan, Liangbing(gan@pku.edu.cn)
英文摘要	Unlike the facile addition of aliphatic amines to fullerenes, heteroaromatic compounds with NH group do not react directly with pristine fullerenes. The present work reports the preparation of several cyclopentadienyl type [60]fullerene derivatives with pyrazole and pyrrole addends through replacement reactions of C (60) Cl (6) in the presence of tetrabutylammonium bromide. The method has also been applied for the synthesis of aniline and methoxyamine [60]fullerene cyclopentadienyl type adducts. Radical species were involved in the reaction mechanism.
资助项目	NNSFC[21672009] ; MOST[2015CB856600] ; RFBR[16-53-52030]
WOS关键词	ELECTROPHILIC AROMATIC-SUBSTITUTION ; CHLOROFULLERENE C60CL6 ; FULLERENE DERIVATIVES ; TERTIARY-AMINES ; ALIPHATIC-AMINES ; C-60 ; FUNCTIONALIZATION ; PHOTOADDITION ; PRECURSORS ; REACTIVITY
WOS研究方向	Chemistry
语种	英语
出版者	GEORG THIEME VERLAG KG
WOS记录号	WOS:000447714400011
资助机构	NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR ; NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR ; NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR ; NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166894]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Gan, Liangbing; Troshin, Pavel A.
作者单位	1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 3.Skolkovo Inst Sci & Technol, Nobel St 3, Moscow 143026, Russia 4.Russian Acad Sci, Inst Problems Chem Phys, Semenov Prospect 1, Chernogolovka 142432, Moscow Region, Russia
推荐引用方式 GB/T 7714	Lou, Ning,Kraevaya, Olga A.,Gan, Liangbing,et al. Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives[J]. SYNTHESIS-STUTTGART,2018,50(21):4283-4289.
APA	Lou, Ning,Kraevaya, Olga A.,Gan, Liangbing,&Troshin, Pavel A..(2018).Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives.SYNTHESIS-STUTTGART,50(21),4283-4289.
MLA	Lou, Ning,et al."Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives".SYNTHESIS-STUTTGART 50.21(2018):4283-4289.