Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity

doi:10.1002/aenm.201803369

	Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity
	Sun, Lei 2; Li, Qiuju 1; Zou, Xu 1; Ai, Xuan 1; Chen, Hui 1; Zou, Xiaoxin 1
刊名	ADVANCED ENERGY MATERIALS
	2019-02-01
卷号	9 期号:5 页码:8
关键词	d-band center electrocatalysis hydrogen evolution reaction metal diboride non-Pt catalysts
ISSN号	1614-6832
DOI	10.1002/aenm.201803369
通讯作者	Zou, Xiaoxin(xxzou@jlu.edu.cn)
英文摘要	Understanding of catalytic trends is an important prerequisite for providing rational guidance toward the prediction of advanced catalysts as well as the development of original materials design principles. A combined theoretical and experimental study that reveals the periodic trends in electrocatalytic activity for the hydrogen evolution reaction (HER) from Group IV B to Group VIII metal diborides is reported here. Theoretical results demonstrate a general linear relationship between the catalytic activity and d-band center of metal diboride, meaning that the latter can serve as a descriptor of activity. And theoretical results also predict ruthenium diboride as the most competitive, nonplatinum candidate among metal diborides for HER because this material has a suitable d-band center and a high density of efficient active sites. Furthermore, the experimental results validate the theoretical activity trends and identify ruthenium diboride as an efficient, pH-universal electrocatalyst with Pt-like activity for HER under both acidic and alkaline media.
资助项目	National Key R&D Program of China[2017YFA0207800] ; National Natural Science Foundation of China (NSFC)[21771079] ; Jilin Province Science and Technology Development Plan[20170101141JC] ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation[161011] ; Postdoctoral Innovative Talent Support Program[BX20180120] ; China Postdoctoral Science Foundation[2018M641771] ; National Natural Science Foundation of China[21621001] ; 111 Project[B17020]
WOS关键词	TOTAL-ENERGY CALCULATIONS ; WATER ; NANOTUBES ; CATALYSIS ; DISSOCIATION ; ADSORPTION ; NANOSHEETS ; NANOWIRES ; POINTS
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science ; Physics
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000459624100010
资助机构	National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Jilin Province Science and Technology Development Plan ; Jilin Province Science and Technology Development Plan ; Young Elite Scientist Sponsorship Program by CAST ; Young Elite Scientist Sponsorship Program by CAST ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Program for JLU Science and Technology Innovative Research Team (JLUSTIRT) ; Fok Ying Tung Education Foundation ; Fok Ying Tung Education Foundation ; Postdoctoral Innovative Talent Support Program ; Postdoctoral Innovative Talent Support Program ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project ; 111 Project
内容类型	期刊论文
源URL	[http://cas-ir.dicp.ac.cn/handle/321008/166012]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者	Zou, Xiaoxin
作者单位	1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China 2.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Sun, Lei,Li, Qiuju,Zou, Xu,et al. Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity[J]. ADVANCED ENERGY MATERIALS,2019,9(5):8.
APA	Sun, Lei,Li, Qiuju,Zou, Xu,Ai, Xuan,Chen, Hui,&Zou, Xiaoxin.(2019).Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity.ADVANCED ENERGY MATERIALS,9(5),8.
MLA	Sun, Lei,et al."Revealing Activity Trends of Metal Diborides Toward pH-Universal Hydrogen Evolution Electrocatalysts with Pt-Like Activity".ADVANCED ENERGY MATERIALS 9.5(2019):8.