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Rheological and tribological properties of ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes
Wang, Baogang1,3; Wang, Xiaobo1; Lou, Wenjing1; Hao, Jingcheng1,2
刊名Journal of physical chemistry c
2010-05-20
卷号114期号:19页码:8749-8754
ISSN号1932-7447
DOI10.1021/jp1005346
通讯作者Lou, wenjing(wjtou@licp.cas.cn)
英文摘要Room temperature ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes (f-mwcnts) were fabricated. transmission electron microscopy (tem), field emission scanning electron microscopy (fe-sem), fourier transform infrared (ft-ir), and x-ray photoelectron spectra revealed the morphology and chemical structure of the obtained f-mwcnts. the rheological behaviors of the f-mwcnts/1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][pf(6)]) nanofluids were studied, demonstrating the shear thinning behavior of nanofluids at rather low concentrations, which could be due to the high specific ratio, flexibility of f-mwcnts, and the formation of a transient network through nanotube nanotube and nanotube matrix interactions. it was found that the rheological behavior of the f-mwcnts (0.1 wt %)/[bmim][pf(6)] nanofluid was similar to that of the surfactant worm-like micelle systems. therefore, the transient network structure of the f-mwcnts (0.1 wt %)/[bmim][pf(6)] nanofluid could be renovated in a short time after shearing forces were input. the shear viscosity of the nanofluids was even lower than that of pure [bmim][pf(6)], especially under high shear rates, which could be attributed to the self-lubrication of f-mwcnts. the tribological properties of the nanofluids were also evaluated in comparison with those of pure [bmim][pf(6)] under loads in the range of 200-800 n, indicating that the nanofluids exhibited preferable friction-reduction properties under 800 n and remarkable antiwear properties with use of reasonable concentrations.
WOS关键词THERMAL-CONDUCTIVITY ; IMIDAZOLIUM CATION ; NANOPARTICLES ; LUBRICANT ; BEHAVIOR ; ELECTROCATALYSIS ; ENHANCEMENT ; SUSPENSIONS ; COMPOSITES ; SOLUBILITY
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000277500000010
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2415429
专题中国科学院大学
通讯作者Lou, Wenjing
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China
2.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Wang, Baogang,Wang, Xiaobo,Lou, Wenjing,et al. Rheological and tribological properties of ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes[J]. Journal of physical chemistry c,2010,114(19):8749-8754.
APA Wang, Baogang,Wang, Xiaobo,Lou, Wenjing,&Hao, Jingcheng.(2010).Rheological and tribological properties of ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes.Journal of physical chemistry c,114(19),8749-8754.
MLA Wang, Baogang,et al."Rheological and tribological properties of ionic liquid-based nanofluids containing functionalized multi-walled carbon nanotubes".Journal of physical chemistry c 114.19(2010):8749-8754.
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