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	Charge-assisted hydrogen-bonded linear second-sphere assemblies [m-ii(dabp)(3)](3)[cr(c2o4)(3)](2)center dot 14h(2)o (m = cu, ni, fe, zn, and mn) with a discrete (h2o)(14) cluster of s-6 symmetry
	Zhuge, Fuyu1,4; Wu, Biao1,2; Dong, Lihuan2; Yang, Jin2; Janiak, Christoph3; Tang, Ning2; Yang, Xiao-Juan1,2
刊名	Australian journal of chemistry
	2010
卷号	63期号:9页码:1358-1364
ISSN号	0004-9425
DOI	10.1071/ch09557
通讯作者	Wu, biao(wubiao@lzb.ac.cn)
英文摘要	A series of isomorphous second-sphere coordination compounds [m-ii(dabp)(3)](3)[cr(c2o4)(3)](2)center dot 14h(2)o (dabp = 5,5'-diamino-2,2'-bipyridine; m = cu (1), ni (2), fe (3), zn (4), and mn (5)) have been constructed through multiple charge-assisted n-h-o- hydrogen-bonding interactions between the oxalate ligands in [cr(c2o4)(3)](3-) (unit b) and the nh2 groups in the [m(dabp)(3)](2+) complex (unit a). the chiral [m(dabp)(3)](2+) cations and [cr(c2o4)(3)](3-) anions with the same lambda (or delta) configuration interdigitate alternately, affording linear a(3)b(2) secondary building units. two adjacent a(3)b(2) units adopting opposite configurations are linked by a six-cornered star-shaped 14-water cluster of s-6 symmetry (unit c) to form a racemic 1d linear chain -a(3)b(2)(lambda)-c-a(3)b(2)(delta)-c-. the microstructure of compound 1 shows a 3d flower-like morphology.
WOS关键词	5,5'-DIAMINO-2,2'-BIPYRIDINE METAL-COMPLEXES ; COORDINATION POLYMERS ; TRANSFER SALTS ; MAGNETIC-PROPERTIES ; BEDT-TTF ; SUPRAMOLECULAR ARCHITECTURES ; WATER SUBSTRUCTURES ; PHYSICAL-PROPERTIES ; CRYSTAL-STRUCTURES ; OPEN FRAMEWORK
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	CSIRO PUBLISHING
WOS记录号	WOS:000281628000007
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2414399
专题	中国科学院大学
通讯作者	Wu, Biao
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 3.Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany 4.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhuge, Fuyu,Wu, Biao,Dong, Lihuan,et al. Charge-assisted hydrogen-bonded linear second-sphere assemblies [m-ii(dabp)(3)](3)[cr(c2o4)(3)](2)center dot 14h(2)o (m = cu, ni, fe, zn, and mn) with a discrete (h2o)(14) cluster of s-6 symmetry[J]. Australian journal of chemistry,2010,63(9):1358-1364.
APA	Zhuge, Fuyu.,Wu, Biao.,Dong, Lihuan.,Yang, Jin.,Janiak, Christoph.,...&Yang, Xiao-Juan.(2010).Charge-assisted hydrogen-bonded linear second-sphere assemblies [m-ii(dabp)(3)](3)[cr(c2o4)(3)](2)center dot 14h(2)o (m = cu, ni, fe, zn, and mn) with a discrete (h2o)(14) cluster of s-6 symmetry.Australian journal of chemistry,63(9),1358-1364.
MLA	Zhuge, Fuyu,et al."Charge-assisted hydrogen-bonded linear second-sphere assemblies [m-ii(dabp)(3)](3)[cr(c2o4)(3)](2)center dot 14h(2)o (m = cu, ni, fe, zn, and mn) with a discrete (h2o)(14) cluster of s-6 symmetry".Australian journal of chemistry 63.9(2010):1358-1364.

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