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Facile controlled synthesis of highly ordered dendritic and flower-like cobalt superstructures
An, Zhenguo1,2; Zhang, Jingjie1; Pan, Shunlong1
刊名Crystengcomm
2010
卷号12期号:2页码:500-506
ISSN号1466-8033
DOI10.1039/b910303a
通讯作者Zhang, jingjie(jjzhang@mail.ipc.ac.cn)
英文摘要Dendritic and flower-like cobalt superstructures have been selectively prepared by a facile hydrothermal route. the synthetic process involves the chemical reduction of cobalt ions and the oriented growth of cobalt nanocrystals under kinetic control independent of surfactants or external magnetic field. the dendritic superstructures are found to be composed of well-aligned metallic cobalt dendrites radiating from the center. upon adding 0.3 m of potassium sodium tartrate (c(4)h(4)knao(6)center dot 4h(2)o) into the reaction system, flower-like cobalt superstructures consisting of spear-like petals attached to a mutual core can be prepared instead of the dendritic ones. the size and morphology of the products can be tailored by properly tuning the process conditions and the component of the reaction solution. the magnetic properties of the products have been studied as well and the results demonstrate that the products present ferromagnetic properties related to the corresponding microstructures. based on a series of contrast experiments, the probable growth mechanism and fabrication process of the products have been proposed. this work provides a facile and effective strategy to fabricate self assembled cobalt hierarchical superstructures with tunable morphologies.
WOS关键词FIELD-INDUCED GROWTH ; MAGNETIC-PROPERTIES ; ROOM-TEMPERATURE ; DOMAIN SHAPES ; CO NANOWIRES ; NANOPARTICLES ; NICKEL ; NANOCRYSTALS ; CRYSTALLINE ; FABRICATION
WOS研究方向Chemistry ; Crystallography
WOS类目Chemistry, Multidisciplinary ; Crystallography
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000273922200028
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2413348
专题中国科学院大学
通讯作者Zhang, Jingjie
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
An, Zhenguo,Zhang, Jingjie,Pan, Shunlong. Facile controlled synthesis of highly ordered dendritic and flower-like cobalt superstructures[J]. Crystengcomm,2010,12(2):500-506.
APA An, Zhenguo,Zhang, Jingjie,&Pan, Shunlong.(2010).Facile controlled synthesis of highly ordered dendritic and flower-like cobalt superstructures.Crystengcomm,12(2),500-506.
MLA An, Zhenguo,et al."Facile controlled synthesis of highly ordered dendritic and flower-like cobalt superstructures".Crystengcomm 12.2(2010):500-506.
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