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	Asymmetric hydrogenation of aromatic ketones using new chiral-bridged diphosphine/diamine-ru(ii) complexes
	Cui, Yu Ming1,4; Wang, Lai Lai1; Kwong, Fuk Yee2,3; Sun, Wei1
刊名	Chinese chemical letters
	2010-12-01
卷号	21期号:12页码:1403-1406
关键词	Asymmetric hydrogenation Chiral alcohols Diphosphine ligand Ruthenium complexes Diamine
ISSN号	1001-8417
DOI	10.1016/j.cclet.2010.05.027
通讯作者	Wang, lai lai(wll@licp.cas.cn)
英文摘要	A series of chiral secondary alcohols were easily prepared by means of asymmetric hydrogenation of prochiral aromatic ketones using a new ((r(ax))-bup)/(r,r)-dpen-ru(ii) complex catalyst system. the hydrogenation of 2-methylacetophenone in n-butanol (t-buok/ru = 45.6/1, s/c = 500, 20 atm. of h(2), 20 degrees c, 48 h) afforded (s)-1-(2'-methylphenyl)ethanol in 92% ee and >99% conversion. (c) 2010 lai lai wang. published by elsevier b.v. on behalf of chinese chemical society. all rights reserved.
WOS关键词	HIGHLY ENANTIOSELECTIVE HYDROGENATION ; STEREOSELECTIVE HYDROGENATION ; DIPHOSPHINE LIGANDS ; EFFICIENT ; CATALYSIS
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	ELSEVIER SCIENCE INC
WOS记录号	WOS:000284389800004
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2412289
专题	中国科学院大学
通讯作者	Wang, Lai Lai
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Hong Kong Polytech Univ, Inst Mol Technol Drug Discovery & Synth, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China 3.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China 4.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Cui, Yu Ming,Wang, Lai Lai,Kwong, Fuk Yee,et al. Asymmetric hydrogenation of aromatic ketones using new chiral-bridged diphosphine/diamine-ru(ii) complexes[J]. Chinese chemical letters,2010,21(12):1403-1406.
APA	Cui, Yu Ming,Wang, Lai Lai,Kwong, Fuk Yee,&Sun, Wei.(2010).Asymmetric hydrogenation of aromatic ketones using new chiral-bridged diphosphine/diamine-ru(ii) complexes.Chinese chemical letters,21(12),1403-1406.
MLA	Cui, Yu Ming,et al."Asymmetric hydrogenation of aromatic ketones using new chiral-bridged diphosphine/diamine-ru(ii) complexes".Chinese chemical letters 21.12(2010):1403-1406.

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