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A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures
Sun, Yirneng1,2; Wei, Zhongming1,2; Xu, Wei1; Zhu, Daoben1
刊名Synthetic metals
2010-11-01
卷号160期号:21-22页码:2371-2376
关键词Polyaniline Nanotube Thermoelectric properties Seebeck coefficient Electrical conductivity Thermal conductivity
ISSN号0379-6779
DOI10.1016/j.synthmet.2010.09.014
通讯作者Xu, wei(wxu@iccas.ac.cn)
英文摘要Beta-naphthalene sulfonic acid doped polyaniline nanotubes (pani nt) was synthesized, a sample without specific nanostructure was prepared as a reference. seebeck coefficient, electrical and thermal conductivity of both samples were studied. for a pani nt prepared with an aniline/nsa ratio of 4:1, the seebeck coefficient had a value of 212.4 mu v/k at 300 k, which was 7 times higher than that of the reference sample. meanwhile, electrical conductivity almost doubled, changed from 0.0045 to 0.0077 s/cm, while the thermal conductivity reduced by 27.5%, dropped from 0.29 to 0.21 w/m k. finally, thermoelectric performance was evaluated by calculating the thermoelectric power factor and figure of merit, and there was a two orders of magnitude's increase for the tube-like pani. a series of pani nts prepared under different aniline/nsa ratio were also investigated for searching an optimized performance. tubular nanostructure was proved to be effective for enhancing the thermoelectric performance. this idea might be applicable to other organic thermoelectric materials as well. (c) 2010 elsevier b.v. all rights reserved.
WOS关键词CONDUCTING POLYMERS ; BULK ALLOYS ; PERFORMANCE ; NANOTUBES ; MICROTUBULES ; TRANSPORT ; NANOWIRES ; FILMS ; ACID
WOS研究方向Materials Science ; Physics ; Polymer Science
WOS类目Materials Science, Multidisciplinary ; Physics, Condensed Matter ; Polymer Science
语种英语
出版者ELSEVIER SCIENCE SA
WOS记录号WOS:000284815400024
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2412128
专题中国科学院大学
通讯作者Xu, Wei
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Sun, Yirneng,Wei, Zhongming,Xu, Wei,et al. A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures[J]. Synthetic metals,2010,160(21-22):2371-2376.
APA Sun, Yirneng,Wei, Zhongming,Xu, Wei,&Zhu, Daoben.(2010).A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures.Synthetic metals,160(21-22),2371-2376.
MLA Sun, Yirneng,et al."A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures".Synthetic metals 160.21-22(2010):2371-2376.
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