QQ客服 官方微博 反馈留言

	Synthesis, structures, and conformational characteristics of triptycene-derived calix[5]arenes
	Tian, Xiao-Hong1,2; Chen, Chuan-Feng1
刊名	Organic letters
	2010-02-05
卷号	12期号:3页码:524-527
ISSN号	1523-7060
DOI	10.1021/ol902758g
通讯作者	Chen, chuan-feng(cchen@iccas.ac.cn)
英文摘要	A series of novel calix[5]arenes 5 containing one 1,8-dimethoxytriptycene moiety were synthesized through an efficient fragment coupling strategy. the subsequent demethylation of 5 with bbr(3) in dry dichloromethane gave the calix[5]arenes 6. debutylation of both 5a similar to b and 6a similar to b with alcl(3) resulted in the same products 7a similar to 7b. the structural studies revealed that all of the macrocyclic compounds have well-defined structures with fixed cone conformations in both solution and solid state. moreover, it was also found that the triptycene-derived calix[5]arenes could encapsulate small neutral molecules in the solid state.
WOS关键词	PARAQUAT DERIVATIVES ; MOLECULAR RECOGNITION ; HIGHLY EFFICIENT ; COMPLEXATION ; HOST ; DESIGN ; SALTS
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000273982600032
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2411204
专题	中国科学院大学
通讯作者	Chen, Chuan-Feng
作者单位	1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Tian, Xiao-Hong,Chen, Chuan-Feng. Synthesis, structures, and conformational characteristics of triptycene-derived calix[5]arenes[J]. Organic letters,2010,12(3):524-527.
APA	Tian, Xiao-Hong,&Chen, Chuan-Feng.(2010).Synthesis, structures, and conformational characteristics of triptycene-derived calix[5]arenes.Organic letters,12(3),524-527.
MLA	Tian, Xiao-Hong,et al."Synthesis, structures, and conformational characteristics of triptycene-derived calix[5]arenes".Organic letters 12.3(2010):524-527.

个性服务

查看访问统计

相关权益政策

暂无数据

收藏/分享

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。