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Synthesis and photovoltaic properties of polythiophene derivatives with side chains containing c-60 end group
He, Youjun1,2; Hou, Jianhui1; Tan, Zhan'ao1; Li, Yongfang1
刊名Journal of applied polymer science
2010-01-05
卷号115期号:1页码:532-539
关键词Donor-acceptor double-cable polymers Polythiophene derivatives Polymer solar cells
ISSN号0021-8995
DOI10.1002/app.30863
通讯作者Li, yongfang(liyf@iccas.ac.cn)
英文摘要A donor-acceptor double-cable polythiophene derivative (pt-f1) with side chain containing c-60 end group was synthesized, and characterized by infrared, uv-vis absorption and photoluminescence (pl) spectroscopy, and electrochemical cyclic voltammetry. cyclic voltammogram of pt-f1 shows the oxidation peak of the polymer main chains and the reduction peaks of the c-60 end groups, indicating that there is no interaction between the polymer main chains and side chain c-60 groups on the ground state. the uv-vis absorption spectrum of pt-f1 film is red-shifted in comparison with that of its chloroform solution. the pl spectrum of the polymer main chain was quenched by the c-60 pendant on the side chain. polymer solar cell with the structure of ito/pedot:pss/pt-f1/ca/a1 was fabricated. the power conversion efficiency of the device based on pt-f1 reached 0.274% under the illumination of am 1.5, 100 mw/cm(2). (c) 2009 wiley periodicals, inc. j appl polym sci 115: 532-539, 2010
WOS关键词DOUBLE-CABLE POLYMERS ; OLIGOTHIOPHENE-FULLERENE TRIADS ; PHOTOINDUCED ELECTRON-TRANSFER ; PLASTIC SOLAR-CELLS ; PENDANT FULLERENES ; PHOTOPHYSICAL PROPERTIES ; CONJUGATED POLYMER ; DEVICES ; BUCKMINSTERFULLERENE ; PERFORMANCE
WOS研究方向Polymer Science
WOS类目Polymer Science
语种英语
出版者WILEY-BLACKWELL
WOS记录号WOS:000271671500066
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2410863
专题中国科学院大学
通讯作者Li, Yongfang
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
He, Youjun,Hou, Jianhui,Tan, Zhan'ao,et al. Synthesis and photovoltaic properties of polythiophene derivatives with side chains containing c-60 end group[J]. Journal of applied polymer science,2010,115(1):532-539.
APA He, Youjun,Hou, Jianhui,Tan, Zhan'ao,&Li, Yongfang.(2010).Synthesis and photovoltaic properties of polythiophene derivatives with side chains containing c-60 end group.Journal of applied polymer science,115(1),532-539.
MLA He, Youjun,et al."Synthesis and photovoltaic properties of polythiophene derivatives with side chains containing c-60 end group".Journal of applied polymer science 115.1(2010):532-539.
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