Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion | |
Liu, Guang-Ning1,2; Guo, Guo-Cong1; Chen, Feng1; Guo, Sheng-Ping1; Jiang, Xiao-Ming1; Yang, Chen1; Wang, Ming-Sheng1; Wu, Mei-Feng1; Huang, Jin-Shun1 | |
刊名 | Crystengcomm
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2010 | |
卷号 | 12期号:12页码:4035-4037 |
ISSN号 | 1466-8033 |
DOI | 10.1039/c0ce00292e |
通讯作者 | Guo, guo-cong(gcguo@fjirsm.ac.cn) |
英文摘要 | The stabilization of the (sns4)(4-) anion in the coordination of [mn(phen)](2+) complexes brings about a novel compound {[mn(phen)](2)(sns4)}(n)center dot nh(2)o (1), in which an unprecedented link mode of the (sns4)(4-) anion is observed. theoretical calculations indicate that tm complexes with big pi-conjugated ligands, such as [mn(phen)](2+), can serve as an excellent electron reservoir to stabilize the (sns4)(4-) anion in 1, despite its strong condensation tendency. magnetic measurements show the presence of strong antiferromagnetic interactions between the mn2+ ions in 1. |
WOS关键词 | TRANSITION-METAL COMPLEX ; CRYSTAL-STRUCTURES ; SOLVOTHERMAL SYNTHESIS ; CHALCOGENIDE CLUSTERS ; LANTHANIDE CLUSTERS ; HYDROTHERMAL SYNTHESIS ; ELECTRONIC-PROPERTIES ; MN-2(L)SB2S5 FAMILY ; INTERNAL LN ; TERNARY |
WOS研究方向 | Chemistry ; Crystallography |
WOS类目 | Chemistry, Multidisciplinary ; Crystallography |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000284266200010 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2409948 |
专题 | 中国科学院大学 |
通讯作者 | Guo, Guo-Cong |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Guang-Ning,Guo, Guo-Cong,Chen, Feng,et al. Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion[J]. Crystengcomm,2010,12(12):4035-4037. |
APA | Liu, Guang-Ning.,Guo, Guo-Cong.,Chen, Feng.,Guo, Sheng-Ping.,Jiang, Xiao-Ming.,...&Huang, Jin-Shun.(2010).Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion.Crystengcomm,12(12),4035-4037. |
MLA | Liu, Guang-Ning,et al."Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion".Crystengcomm 12.12(2010):4035-4037. |
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