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	Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion
	Liu, Guang-Ning1,2; Guo, Guo-Cong1; Chen, Feng1; Guo, Sheng-Ping1; Jiang, Xiao-Ming1; Yang, Chen1; Wang, Ming-Sheng1; Wu, Mei-Feng1; Huang, Jin-Shun1
刊名	Crystengcomm
	2010
卷号	12期号:12页码:4035-4037
ISSN号	1466-8033
DOI	10.1039/c0ce00292e
通讯作者	Guo, guo-cong(gcguo@fjirsm.ac.cn)
英文摘要	The stabilization of the (sns4)(4-) anion in the coordination of [mn(phen)](2+) complexes brings about a novel compound {[mn(phen)](2)(sns4)}(n)center dot nh(2)o (1), in which an unprecedented link mode of the (sns4)(4-) anion is observed. theoretical calculations indicate that tm complexes with big pi-conjugated ligands, such as [mn(phen)](2+), can serve as an excellent electron reservoir to stabilize the (sns4)(4-) anion in 1, despite its strong condensation tendency. magnetic measurements show the presence of strong antiferromagnetic interactions between the mn2+ ions in 1.
WOS关键词	TRANSITION-METAL COMPLEX ; CRYSTAL-STRUCTURES ; SOLVOTHERMAL SYNTHESIS ; CHALCOGENIDE CLUSTERS ; LANTHANIDE CLUSTERS ; HYDROTHERMAL SYNTHESIS ; ELECTRONIC-PROPERTIES ; MN-2(L)SB2S5 FAMILY ; INTERNAL LN ; TERNARY
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Multidisciplinary ; Crystallography
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000284266200010
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2409948
专题	中国科学院大学
通讯作者	Guo, Guo-Cong
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Liu, Guang-Ning,Guo, Guo-Cong,Chen, Feng,et al. Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion[J]. Crystengcomm,2010,12(12):4035-4037.
APA	Liu, Guang-Ning.,Guo, Guo-Cong.,Chen, Feng.,Guo, Sheng-Ping.,Jiang, Xiao-Ming.,...&Huang, Jin-Shun.(2010).Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion.Crystengcomm,12(12),4035-4037.
MLA	Liu, Guang-Ning,et al."Stabilization of (sns4)(4-) anion by coordinating to [tm(pi-conjugated-ligand)(m)](n+) complex: a chain-like thiostannate(iv) {[mn(phen)](2)(sns4)}(n)center dot nh(2)o exhibiting an unprecedented link mode of the (sns4)(4-) anion".Crystengcomm 12.12(2010):4035-4037.

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