The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones | |
Xue, Zhou-Yang1,2; Jiang, Yan1,2; Peng, Xiao-Zhi1,2; Yuan, Wei-Cheng1; Zhang, Xiao-Mei1 | |
刊名 | Advanced synthesis & catalysis
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2010-09-01 | |
卷号 | 352期号:13页码:2132-2136 |
关键词 | Dihydrobenzoxazinones Dihydroquinoxalinones Enantioselective hydrosilylation Lewis bases Organocatalysis |
ISSN号 | 1615-4150 |
DOI | 10.1002/adsc.201000274 |
通讯作者 | Zhang, xiao-mei(xmzhang@cioc.ac.cn) |
英文摘要 | The first general, highly enantioselective hydrosilylation of benzoxazinones and quinoxalinones has been developed. the chiral lewis base organocatalysts that are readily accessible from (1s,2r)-ephedrine and (1r,2s)-ephedrine promoted the title reaction to afford various chiral dihydrobenzoxazinones and dihydroquinoxalinones with good yields as well as good enantioselectivities. |
WOS关键词 | AMINO-ACID-DERIVATIVES ; DIELS-ALDER REACTIONS ; BENZODIAZEPINE-RECEPTOR ; PARTIAL AGONIST ; REDUCTION ; TRICHLOROSILANE ; IMINES ; POTENT ; ANTAGONIST ; AMIDES |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Applied ; Chemistry, Organic |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000282621700005 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2409274 |
专题 | 中国科学院大学 |
通讯作者 | Zhang, Xiao-Mei |
作者单位 | 1.Chinese Acad Sci, Key Lab Asymmetr Synth & Chiraltechnol Sichuan Pr, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Xue, Zhou-Yang,Jiang, Yan,Peng, Xiao-Zhi,et al. The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones[J]. Advanced synthesis & catalysis,2010,352(13):2132-2136. |
APA | Xue, Zhou-Yang,Jiang, Yan,Peng, Xiao-Zhi,Yuan, Wei-Cheng,&Zhang, Xiao-Mei.(2010).The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones.Advanced synthesis & catalysis,352(13),2132-2136. |
MLA | Xue, Zhou-Yang,et al."The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones".Advanced synthesis & catalysis 352.13(2010):2132-2136. |
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