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The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones
Xue, Zhou-Yang1,2; Jiang, Yan1,2; Peng, Xiao-Zhi1,2; Yuan, Wei-Cheng1; Zhang, Xiao-Mei1
刊名Advanced synthesis & catalysis
2010-09-01
卷号352期号:13页码:2132-2136
关键词Dihydrobenzoxazinones Dihydroquinoxalinones Enantioselective hydrosilylation Lewis bases Organocatalysis
ISSN号1615-4150
DOI10.1002/adsc.201000274
通讯作者Zhang, xiao-mei(xmzhang@cioc.ac.cn)
英文摘要The first general, highly enantioselective hydrosilylation of benzoxazinones and quinoxalinones has been developed. the chiral lewis base organocatalysts that are readily accessible from (1s,2r)-ephedrine and (1r,2s)-ephedrine promoted the title reaction to afford various chiral dihydrobenzoxazinones and dihydroquinoxalinones with good yields as well as good enantioselectivities.
WOS关键词AMINO-ACID-DERIVATIVES ; DIELS-ALDER REACTIONS ; BENZODIAZEPINE-RECEPTOR ; PARTIAL AGONIST ; REDUCTION ; TRICHLOROSILANE ; IMINES ; POTENT ; ANTAGONIST ; AMIDES
WOS研究方向Chemistry
WOS类目Chemistry, Applied ; Chemistry, Organic
语种英语
出版者WILEY-V C H VERLAG GMBH
WOS记录号WOS:000282621700005
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2409274
专题中国科学院大学
通讯作者Zhang, Xiao-Mei
作者单位1.Chinese Acad Sci, Key Lab Asymmetr Synth & Chiraltechnol Sichuan Pr, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Xue, Zhou-Yang,Jiang, Yan,Peng, Xiao-Zhi,et al. The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones[J]. Advanced synthesis & catalysis,2010,352(13):2132-2136.
APA Xue, Zhou-Yang,Jiang, Yan,Peng, Xiao-Zhi,Yuan, Wei-Cheng,&Zhang, Xiao-Mei.(2010).The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones.Advanced synthesis & catalysis,352(13),2132-2136.
MLA Xue, Zhou-Yang,et al."The first general, highly enantioselective lewis base organocatalyzed hydrosilylation of benzoxazinones and quinoxalinones".Advanced synthesis & catalysis 352.13(2010):2132-2136.
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