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	Preparation and characterization of a new carbonaceous material for electrochemical systems
	Lin, Zi Ji1,2,3; Hu, Xue Bu1,2,3; Huai, Yong Jian1,2,3; Deng, Zheng Hua1,2,3
刊名	Journal of the serbian chemical society
	2010
卷号	75期号:2页码:271-282
关键词	Pyrolytic carbon Scrap tire rubber Carbonaceous materials Electrochemical performance Coulombic efficiency Chemical diffusion coefficient
ISSN号	0352-5139
DOI	10.2298/jsc10020271l
通讯作者	Deng, zheng hua(zhdeng@cioc.ac.cn)
英文摘要	A new carbonaceous material was successfully prepared by the pyrolysis of scrap tire rubber at 600 degrees c under a nitrogen atmosphere. the physical characteristics of the prepared carbonaceous material were studied by scanning electron microscopy (sem), x-ray powder diffraction (xrd) and x-ray photoelectron spectroscopy (xps). it was proved that the carbonaceous material had a disordered structure and spherical morphology with an average particle size about 100 run. the prepared carbonaceous material was also used as electrodes in electrochemical systems to examine its electrochemical performances. it was demonstrated that it delivered a lithium insertion capacity of 658 ma h g(-1) during the first cycle with a coulombic efficiency of 68%. cyclic voltammograms test results showed that a redox reaction occurred during the cycles. the chemical diffusion coefficient based on the impedance diagram was about 10(-10) cm(2) s(-1). the pyrolytic carbonaceous material derived from scrap tire rubber is therefore considered to be a potential anode material in lithium secondary batteries or capacitors. furthermore, it is advantageous for mental protection.
WOS关键词	ANODE MATERIALS ; DISORDERED CARBONS ; LITHIUM INSERTION ; NEGATIVE-ELECTRODE ; ION BATTERIES ; PEANUT SHELLS ; MECHANISM ; INTERCALATION ; DIFFUSION ; STORAGE
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
语种	英语
出版者	SERBIAN CHEMICAL SOC
WOS记录号	WOS:000275840200012
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2408393
专题	中国科学院大学
通讯作者	Deng, Zheng Hua
作者单位	1.Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Zhongke Laifang Power Sci & Tecnol Co Ltd, Chengdu 610041, Sichuan, Peoples R China
推荐引用方式 GB/T 7714	Lin, Zi Ji,Hu, Xue Bu,Huai, Yong Jian,et al. Preparation and characterization of a new carbonaceous material for electrochemical systems[J]. Journal of the serbian chemical society,2010,75(2):271-282.
APA	Lin, Zi Ji,Hu, Xue Bu,Huai, Yong Jian,&Deng, Zheng Hua.(2010).Preparation and characterization of a new carbonaceous material for electrochemical systems.Journal of the serbian chemical society,75(2),271-282.
MLA	Lin, Zi Ji,et al."Preparation and characterization of a new carbonaceous material for electrochemical systems".Journal of the serbian chemical society 75.2(2010):271-282.

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