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	Synthesis of a bis-macrotricyclic host and its complexation with secondary ammonium salts: an acid-base switchable molecular handcuff
	Guo, Jia-Bin1,2; Xiang, Jun-Feng1; Chen, Chuan-Feng1
刊名	European journal of organic chemistry
	2010-09-01
期号	26页码:5056-5062
关键词	Self-assembly Structure elucidation Host-guest systems Macrocycles
ISSN号	1434-193X
DOI	10.1002/ejoc.201000675
通讯作者	Chen, chuan-feng(cchen@iccas.ac.cn)
英文摘要	A novel triptycene-derived bis-macrotricyclic host was designed and synthesized. the host was shown to form a 1:4 stable complex with 4 equiv. of dibenzylammonium salt in solution and in the solid state. moreover, it was found that the host with multicavities could also self-assemble with 2 equiv. of bis-secondary ammonium salt to form a handcuff-like structure under the tested condition ([1](0) = 3.0 mm). the complexation and decomplexation of the assembly could be further chemically controlled by the stimuli of acid and base.
WOS关键词	BIS(CROWN ETHER) HOST ; SUPRAMOLECULAR CHEMISTRY ; PARAQUAT DERIVATIVES ; GUESTS ; DRIVEN ; IONS ; COOPERATIVITY ; MULTIVALENCY ; RECOGNITION ; POLYETHERS
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	WILEY-BLACKWELL
WOS记录号	WOS:000282777400011
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2407836
专题	中国科学院大学
通讯作者	Chen, Chuan-Feng
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Guo, Jia-Bin,Xiang, Jun-Feng,Chen, Chuan-Feng. Synthesis of a bis-macrotricyclic host and its complexation with secondary ammonium salts: an acid-base switchable molecular handcuff[J]. European journal of organic chemistry,2010(26):5056-5062.
APA	Guo, Jia-Bin,Xiang, Jun-Feng,&Chen, Chuan-Feng.(2010).Synthesis of a bis-macrotricyclic host and its complexation with secondary ammonium salts: an acid-base switchable molecular handcuff.European journal of organic chemistry(26),5056-5062.
MLA	Guo, Jia-Bin,et al."Synthesis of a bis-macrotricyclic host and its complexation with secondary ammonium salts: an acid-base switchable molecular handcuff".European journal of organic chemistry .26(2010):5056-5062.

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