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	Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes
	Wang, Peng1,2,3; Chen, Junmin1,2,3,4; Cun, Linfeng1,2; Deng, Jingen1,2,3; Zhu, Jin1,2,3; Liao, Jian1,2,3
刊名	Organic & biomolecular chemistry
	2009
卷号	7期号:18页码:3741-3747
ISSN号	1477-0520
DOI	10.1039/b909850j
通讯作者	Liao, jian(jliao10@cioc.ac.cn)
英文摘要	A series of enantiomerically pure mono- and bis-aryl tert-butyl sulfoxides were synthesised to promote the enantioselective allylation of aldehydes with allyltrichlorosilane. moderate to good yields and modest to high enantioselectivities were achieved. the absence of nonlinear effect, spacer effect, promoter loading and concentration effect indicate that only one molecule of aryl tert-butyl sulfoxide is involved in the stereodetermining step.
WOS关键词	CATALYTIC ASYMMETRIC ALLYLATION ; PHOSPHORUS-BASED AMIDES ; CHIRAL LEWIS-BASES ; PYRIDINE N-OXIDES ; ALLYLIC TRICHLOROSILANES ; BUTANESULFINYL IMINES ; HOMOALLYLIC ALCOHOLS ; AROMATIC-ALDEHYDES ; BIS(SULFINYL)IMIDOAMIDINE LIGANDS ; ORGANOCATALYSTS
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000269327500017
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2404078
专题	中国科学院大学
通讯作者	Liao, Jian
作者单位	1.Chinese Acad Sci, Chengdu Inst Organ Chem, Natl Engn Res Ctr Chiral Drugs, Chengdu 610041, Peoples R China 2.Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China
推荐引用方式 GB/T 7714	Wang, Peng,Chen, Junmin,Cun, Linfeng,et al. Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes[J]. Organic & biomolecular chemistry,2009,7(18):3741-3747.
APA	Wang, Peng,Chen, Junmin,Cun, Linfeng,Deng, Jingen,Zhu, Jin,&Liao, Jian.(2009).Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes.Organic & biomolecular chemistry,7(18),3741-3747.
MLA	Wang, Peng,et al."Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes".Organic & biomolecular chemistry 7.18(2009):3741-3747.

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