Study of magic-size-cluster mediated formation of cds nanocrystals: properties of the magic-size clusters and mechanism implication | |
Yu, Qiyu1,2; Liu, Chun-Yan1 | |
刊名 | Journal of physical chemistry c
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2009-07-23 | |
卷号 | 113期号:29页码:12766-12771 |
ISSN号 | 1932-7447 |
DOI | 10.1021/jp903199y |
通讯作者 | Liu, chun-yan(cyliu@mail.ipc.ac.cn) |
英文摘要 | The magic-size clusters (mscs) of semiconductor nanocrystals (ncs) have attracted much attention the last few years. in this work, we studied the synthesis of cds ncs in a liquid-paraffin/glycerol biphasic system at different temperatures. the properties of a 323-nm-absorbing msc species, an intermediate in the synthesis, were investigated using an ultraviolet-visible (uv-vis) spectroscopic technique. alcohol-induced transformations of the mscs into a similar to 309-nm-absorbing and/or a similar to 348-nm-absorbing cluster/crystal species were studied in detail. based on the studies, a plausible nucleation-growth mechanism was proposed for the msc-mediated formation of cds ncs. |
WOS关键词 | II-VI ; SEMICONDUCTOR NANOCRYSTALS ; QUANTUM DOTS ; GROWTH ; MONODISPERSE ; NANOPARTICLES ; NUCLEATION ; CDTE ; LUMINESCENT ; PRECURSORS |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
语种 | 英语 |
出版者 | AMER CHEMICAL SOC |
WOS记录号 | WOS:000268139800024 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2403562 |
专题 | 中国科学院大学 |
通讯作者 | Liu, Chun-Yan |
作者单位 | 1.Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Yu, Qiyu,Liu, Chun-Yan. Study of magic-size-cluster mediated formation of cds nanocrystals: properties of the magic-size clusters and mechanism implication[J]. Journal of physical chemistry c,2009,113(29):12766-12771. |
APA | Yu, Qiyu,&Liu, Chun-Yan.(2009).Study of magic-size-cluster mediated formation of cds nanocrystals: properties of the magic-size clusters and mechanism implication.Journal of physical chemistry c,113(29),12766-12771. |
MLA | Yu, Qiyu,et al."Study of magic-size-cluster mediated formation of cds nanocrystals: properties of the magic-size clusters and mechanism implication".Journal of physical chemistry c 113.29(2009):12766-12771. |
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