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	Effect of electrostatic interactions on metallophthalocyanine single molecular arrays with n-octadecyl mercaptan templates
	Kong, Xianghua2,3; Deng, Ke1; Yang, Yanlian1; Lei, Shengbin1; Wang, Chen1
刊名	Journal of nanoscience and nanotechnology
	2009-02-01
卷号	9期号:2页码:1152-1155
关键词	Scanning tunneling microscopy Single molecular array Metallophthalocyanine Density functional theory
ISSN号	1533-4880
DOI	10.1166/jnn.2009.c108
通讯作者	Wang, chen()
英文摘要	By changing central metal ions or by tuning the length of substituted alkyl chains, metallophthalocyanines or their derivatives exhibit various assembling behaviors when co-adsorbed with n-octadecyl mercaptan on highly oriented pyrolytic graphite surfaces. repeated scanning tunneling microscopy experiments demonstrate that planar or short alkyl chain substituted mpcs could form single molecular arrays while phase separation occurred when non-planar or longer alkyl chain substituted mpcs were co-adsorbed with c18sh templates. the experimental results combined with the density functional theory calculations reveal that intermolecular electrostatic and van der waals interactions play essential roles in the formation of single molecular arrays.
WOS关键词	SCANNING-TUNNELING-MICROSCOPY ; PHTHALOCYANINE ; NANOSTRUCTURES ; SPECTROSCOPY ; ADSORBATES ; AU(111) ; SURFACE
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
语种	英语
出版者	AMER SCIENTIFIC PUBLISHERS
WOS记录号	WOS:000263653300108
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2402694
专题	中国科学院大学
通讯作者	Wang, Chen
作者单位	1.Natl Ctr Nanosci & Technol, Beijing 100080, Peoples R China 2.CAS, Inst Chem, Beijing 100080, Peoples R China 3.CAS, Grad Sch, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Kong, Xianghua,Deng, Ke,Yang, Yanlian,et al. Effect of electrostatic interactions on metallophthalocyanine single molecular arrays with n-octadecyl mercaptan templates[J]. Journal of nanoscience and nanotechnology,2009,9(2):1152-1155.
APA	Kong, Xianghua,Deng, Ke,Yang, Yanlian,Lei, Shengbin,&Wang, Chen.(2009).Effect of electrostatic interactions on metallophthalocyanine single molecular arrays with n-octadecyl mercaptan templates.Journal of nanoscience and nanotechnology,9(2),1152-1155.
MLA	Kong, Xianghua,et al."Effect of electrostatic interactions on metallophthalocyanine single molecular arrays with n-octadecyl mercaptan templates".Journal of nanoscience and nanotechnology 9.2(2009):1152-1155.

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