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Preparation of hierarchical polystyrene microsphere (core)/mcm-41 nanoparticle (shell) composite particles via electrostatic layer-by-layer assembly
Du Xin1,2; Liu Xiangmei1,2; Zheng Yi1; He Jinhui1
刊名Acta chimica sinica
2009-03-14
卷号67期号:5页码:435-441
关键词Composite microparticle Polystyrene microsphere Mcm-41 nanoparticle Electrostatic layer-by-layer assembly
ISSN号0567-7351
通讯作者Du xin()
英文摘要Mcm-41 nanoparticles were successfully coated on the surface of polystyrene (ps) microspheres via electrostatic layer-by-layer assembly by using two polyelectrolytes, i.e., sodium poly(4-styrenesulfonate) (pss) and poly(diallyldimethylammonium) (pdda). the experimental results showed that when monodisperse ps microspheres of ca. 1.4 mu m in diameter were used as core, composite microparticles coated with two prime polyelectrolyte bilayers (pdda/pss)(2), i.e., ps(pdda/pss)2(pdda/mcm-41), aggregated to a less extent than those coated with a single prime polyelectrolyte bilayer (pdda/pss), i.e., ps(pdda/pss)(pdda/mcm-41). however, the covering of mcm-41 nanoparticles was incompact on the surface of ps microspheres in both cases, and there were many impurities in the final products. when monodisperse ps microspheres of 5 mu m in diameter were used as core, mcm-41 nanoparticles were densely coated on the surface of ps microspheres.
WOS关键词HOLLOW SPHERES ; DISPERSION POLYMERIZATION ; METAL NANOPARTICLES ; SILICA ; FABRICATION ; TEMPLATES ; COATINGS ; RELEASE ; SIZE
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
语种英语
出版者SCIENCE PRESS
WOS记录号WOS:000264781500014
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2402282
专题中国科学院大学
通讯作者Du Xin
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Funct Nanomat Lab, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Du Xin,Liu Xiangmei,Zheng Yi,et al. Preparation of hierarchical polystyrene microsphere (core)/mcm-41 nanoparticle (shell) composite particles via electrostatic layer-by-layer assembly[J]. Acta chimica sinica,2009,67(5):435-441.
APA Du Xin,Liu Xiangmei,Zheng Yi,&He Jinhui.(2009).Preparation of hierarchical polystyrene microsphere (core)/mcm-41 nanoparticle (shell) composite particles via electrostatic layer-by-layer assembly.Acta chimica sinica,67(5),435-441.
MLA Du Xin,et al."Preparation of hierarchical polystyrene microsphere (core)/mcm-41 nanoparticle (shell) composite particles via electrostatic layer-by-layer assembly".Acta chimica sinica 67.5(2009):435-441.
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