CORC  > 中国科学院大学
Thermal behavior of isotactic polypropylene in different content of beta-nucleating agent
Xu, Linli1,2,3; Xu, Kai1,2; Chen, Dehong1,2,3; Zheng, Qiukai1,2,3; Liu, Feiyue1,2,3; Chen, Mingcai1,2
刊名Journal of thermal analysis and calorimetry
2009-06-01
卷号96期号:3页码:733-740
关键词Isotactic polypropylene Beta-phase Beta-form Beta-nucleating agent Dsc Recrystallization/reorganization
ISSN号1388-6150
DOI10.1007/s10973-009-0022-7
通讯作者Chen, mingcai(mcchen@gic.ac.cn)
英文摘要The effects of non-isothermal and isothermal crystallization on the formation of alpha- and beta-phase in isotactic polypropylene (ipp) with different content of beta-nucleating agent are investigated by differential scanning calorimetry (dsc). on non-isothermal crystallization, the content of beta-phase and regularity of its crystals are depended on both cooling rate and the content of beta-nucleating agent. the faster cooling rate is, the lower of melting peak temperature (t(mp)) and crystallization peak temperature (t(cp)) of alpha- and beta-phase are. the enthalpy of fusion (a dagger h) of beta-phase increases with cooling rate in a certain range for the sample with 0.1 wt% beta-nucleating agent (g(1)) and decreases for that with 0.3 wt% beta-nucleating agent (g(3)). on isothermal crystallization, the enthalpy of fusion of beta-phase in g(1) is higher than in g(3) which is related to the efficiency of nucleation in different concentration of nucleating center in two samples.
WOS关键词MELTING BEHAVIOR ; SUPERMOLECULAR STRUCTURE ; DEFORMATION MECHANISMS ; CRYSTALLINE ORDER ; PHASE ; ALPHA ; GROWTH ; NECKING ; FORMS
WOS研究方向Chemistry
WOS类目Chemistry, Analytical ; Chemistry, Physical
语种英语
出版者SPRINGER
WOS记录号WOS:000268583900009
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2399126
专题中国科学院大学
通讯作者Chen, Mingcai
作者单位1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China
2.Guangdong Key Lab Elect Organ Polymer Mat, Guangzhou 510650, Guangdong, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Xu, Linli,Xu, Kai,Chen, Dehong,et al. Thermal behavior of isotactic polypropylene in different content of beta-nucleating agent[J]. Journal of thermal analysis and calorimetry,2009,96(3):733-740.
APA Xu, Linli,Xu, Kai,Chen, Dehong,Zheng, Qiukai,Liu, Feiyue,&Chen, Mingcai.(2009).Thermal behavior of isotactic polypropylene in different content of beta-nucleating agent.Journal of thermal analysis and calorimetry,96(3),733-740.
MLA Xu, Linli,et al."Thermal behavior of isotactic polypropylene in different content of beta-nucleating agent".Journal of thermal analysis and calorimetry 96.3(2009):733-740.
个性服务
查看访问统计
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。


©版权所有 ©2017 CSpace - Powered by CSpace