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Photo-catalytic h-2 evolution over a series of keggin-structure heteropoly blue sensitized pt/tio2 under visible light irradiation
Fu, Ning1,2; Lu, Gongxuan1
刊名Applied surface science
2009-02-01
卷号255期号:8页码:4378-4383
关键词Heteropoly blue (hpb) Visible light Sensitization Tio2
ISSN号0169-4332
DOI10.1016/j.apsusc.2008.11.056
通讯作者Lu, gongxuan(gxlu@lzb.ac.cn)
英文摘要We report the visible light-induced hydrogen generation over a series of keggin-structure heteropoly blue (hpb) anions (pw12o403), phosphotungstic blue (ptb), gew12o404 (gtb), siw12o404 (stb), bw12o405 (btb)) sensitized pt/tio2 photo-catalysts. the sensitization of tio2 by hpb was certified using photo-electrochemical measurements and uv-vis absorption spectra. ptb showed the most pronounced sensitization effect for tio2 in those hpb anions and pt/tio2-ptb showed the highest hydrogen generation activity. the sensitization of tio2 was significantly dependent on the reduction potential of hpa, which was determined by the kind of central atom in hpa. (c) 2008 elsevier b. v. all rights reserved.
WOS关键词PHOTOSYNTHETIC REACTION-CENTER ; PHOTOCATALYTIC DECOMPOSITION ; HYDROGEN EVOLUTION ; ORGANIC-COMPOUNDS ; WATER ; REDUCTION ; TIO2 ; SEMICONDUCTOR ; ACID ; OXIDATION
WOS研究方向Chemistry ; Materials Science ; Physics
WOS类目Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000262695200004
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2398598
专题中国科学院大学
通讯作者Lu, Gongxuan
作者单位1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Fu, Ning,Lu, Gongxuan. Photo-catalytic h-2 evolution over a series of keggin-structure heteropoly blue sensitized pt/tio2 under visible light irradiation[J]. Applied surface science,2009,255(8):4378-4383.
APA Fu, Ning,&Lu, Gongxuan.(2009).Photo-catalytic h-2 evolution over a series of keggin-structure heteropoly blue sensitized pt/tio2 under visible light irradiation.Applied surface science,255(8),4378-4383.
MLA Fu, Ning,et al."Photo-catalytic h-2 evolution over a series of keggin-structure heteropoly blue sensitized pt/tio2 under visible light irradiation".Applied surface science 255.8(2009):4378-4383.
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