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	Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation
	Chen Li-Mei1,2; Liu Xia1; Jiang Sheng-Xiang1
刊名	Chinese journal of analytical chemistry
	2009-02-01
卷号	37期号:2页码:255-258
关键词	Cellulose tris(3, 5-dimethylphenylcarbamate) Chiral stationary phase Interactions Linear solvation energy relationship Support
ISSN号	0253-3820
通讯作者	Liu xia(gsliuxia@lzb.ac.cn)
英文摘要	Linear solvation energy relationships (lser) were used to evaluate the interactions exited on cellulose tris (3, 5-dimethylphenylcarbamate) (cdmpc)-chiral stationary phase (csp) and the effect of the support on the chiral separation. the 33 solutes descriptors and their retention factors were used to the multiple linear regressions analysis and statistical calculations. and the interaction existed in the chiral stationary phases was evaluated by the system parameters obtained by the multiple linear regression analysis. there are weaker pi-pi interactions and stronger dipole- or induced dipole-type interactions on the chiral stationary phases in normal phase. and the h-bond existed in the chiral stationary phase is affected by the support. csp with aminopropy silica gel(aps) support has the stronger ability of h-bond donor, and csp with sio(2) support has the stronger ability of h-bond acceptor.
WOS关键词	PERFORMANCE LIQUID-CHROMATOGRAPHY ; SOLVATION ENERGY RELATIONSHIPS ; SILICA-GEL ; RECOGNITION ; ENANTIOMERS ; RESOLUTION
WOS研究方向	Chemistry
WOS类目	Chemistry, Analytical
语种	英语
出版者	ELSEVIER SCIENCE INC
WOS记录号	WOS:000265169000018
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2398565
专题	中国科学院大学
通讯作者	Liu Xia
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Key Lab Nat Med Gansu Prov, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Chen Li-Mei,Liu Xia,Jiang Sheng-Xiang. Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation[J]. Chinese journal of analytical chemistry,2009,37(2):255-258.
APA	Chen Li-Mei,Liu Xia,&Jiang Sheng-Xiang.(2009).Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation.Chinese journal of analytical chemistry,37(2),255-258.
MLA	Chen Li-Mei,et al."Characterisation of the interactions of coated cellulose tris(3,5-dimethylphenylcarbamate)-chiral stationary phase and the effect of support on chiral separation".Chinese journal of analytical chemistry 37.2(2009):255-258.

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