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Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones
Xu, Li-Wen1,2,3; Yang, Ming-Song1; Qiu, Hua-Yu1; Lai, Guo-Qiao1; Jiang, Jian-Xiong1
刊名Synthetic communications
2008
卷号38期号:7页码:1011-1019
关键词Enones Iron Lewis acid Michael addition Sakurai reaction
ISSN号0039-7911
DOI10.1080/00397910701860646
通讯作者Xu, li-wen(licpxulw@yahoo.com)
英文摘要A general catalytic conjugate addition with allyltrimethylsilane and chalcones is described. allyltrimethylsilane undergoes the sakurai-michael reaction smoothly with high chemoselectivity in the presence of a catalytic amount of fecl(3)/tmscl under very mild and convenient conditions to afford the corresponding michael adducts in high yields.
WOS关键词ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ; STOICHIOMETRIC ORGANOCOPPER REAGENTS ; ACCELERATED CONJUGATE ADDITION ; SILICON-CONTAINING COMPOUNDS ; ORGANOSILICON COMPOUNDS ; ORGANIC-SYNTHESIS ; DUAL ACTIVATION ; ALLYLSILANES ; INDIUM ; ALLYLATION
WOS研究方向Chemistry
WOS类目Chemistry, Organic
语种英语
出版者TAYLOR & FRANCIS INC
WOS记录号WOS:000256530700002
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2392613
专题中国科学院大学
通讯作者Xu, Li-Wen
作者单位1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxosynth & Select Oxidat, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Grad Sch, Lanzhou, Peoples R China
推荐引用方式
GB/T 7714
Xu, Li-Wen,Yang, Ming-Song,Qiu, Hua-Yu,et al. Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones[J]. Synthetic communications,2008,38(7):1011-1019.
APA Xu, Li-Wen,Yang, Ming-Song,Qiu, Hua-Yu,Lai, Guo-Qiao,&Jiang, Jian-Xiong.(2008).Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones.Synthetic communications,38(7),1011-1019.
MLA Xu, Li-Wen,et al."Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones".Synthetic communications 38.7(2008):1011-1019.
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