Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones | |
Xu, Li-Wen1,2,3; Yang, Ming-Song1; Qiu, Hua-Yu1; Lai, Guo-Qiao1; Jiang, Jian-Xiong1 | |
刊名 | Synthetic communications
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2008 | |
卷号 | 38期号:7页码:1011-1019 |
关键词 | Enones Iron Lewis acid Michael addition Sakurai reaction |
ISSN号 | 0039-7911 |
DOI | 10.1080/00397910701860646 |
通讯作者 | Xu, li-wen(licpxulw@yahoo.com) |
英文摘要 | A general catalytic conjugate addition with allyltrimethylsilane and chalcones is described. allyltrimethylsilane undergoes the sakurai-michael reaction smoothly with high chemoselectivity in the presence of a catalytic amount of fecl(3)/tmscl under very mild and convenient conditions to afford the corresponding michael adducts in high yields. |
WOS关键词 | ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS ; STOICHIOMETRIC ORGANOCOPPER REAGENTS ; ACCELERATED CONJUGATE ADDITION ; SILICON-CONTAINING COMPOUNDS ; ORGANOSILICON COMPOUNDS ; ORGANIC-SYNTHESIS ; DUAL ACTIVATION ; ALLYLSILANES ; INDIUM ; ALLYLATION |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
语种 | 英语 |
出版者 | TAYLOR & FRANCIS INC |
WOS记录号 | WOS:000256530700002 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2392613 |
专题 | 中国科学院大学 |
通讯作者 | Xu, Li-Wen |
作者单位 | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxosynth & Select Oxidat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Grad Sch, Lanzhou, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Li-Wen,Yang, Ming-Song,Qiu, Hua-Yu,et al. Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones[J]. Synthetic communications,2008,38(7):1011-1019. |
APA | Xu, Li-Wen,Yang, Ming-Song,Qiu, Hua-Yu,Lai, Guo-Qiao,&Jiang, Jian-Xiong.(2008).Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones.Synthetic communications,38(7),1011-1019. |
MLA | Xu, Li-Wen,et al."Efficient iron-catalyzed sakurai-michael addition of allyltrimethylsilane to chalcones".Synthetic communications 38.7(2008):1011-1019. |
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