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	A mercury(ii)-radical complex with a 1d ladder structure
	Zhang, Jian-Ying1,2; Liu, Cai-Ming1; Zhang, De-Qing1; Zhu, Dao-Ben1
刊名	Journal of coordination chemistry
	2008
卷号	61期号:8页码:1325-1332
关键词	Nitronyl nitroxide complex Mercury complex Ladder structure Magnetic properties
ISSN号	0095-8972
DOI	10.1080/00958970701598951
通讯作者	Liu, cai-ming(cmliu@iccas.ac.cn)
英文摘要	Interaction of hgi2 with a new long rigid nitronyl nitroxide radical ligand, 2-[4-(2-pyridin-4-yl-vinyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (l), leads to the formation of the mercury-radical complex [hg2i4l2](n) (1). the single crystal structure analysis reveals that 1 exhibits a one-dimensional (1d) ladder structure. magnetic susceptibility data of 1 were simulated by a uniform chain model composed of the nit-nit dimers, indicating that there exist an antiferromagnetic exchange between the nitroxides within the dimer (j(1) = -8.41 cm(-1)) and a very weak interdimer antiferromagnetic interaction (j(c) = -0.39 cm(-1)).
WOS关键词	NITRONYL NITROXIDE RADICALS ; MOLECULAR MAGNETIC NANOWIRES ; PYRIDYL-SUBSTITUTED NITRONYL ; TRANSITION-METAL DICATIONS ; CRYSTAL-STRUCTURE ; FERROMAGNETIC INTERACTIONS ; COORDINATION-COMPLEXES ; MANGANESE(II) COMPLEXES ; BRIDGED COPPER(II) ; SILVER(I) COMPLEX
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
语种	英语
出版者	TAYLOR & FRANCIS LTD
WOS记录号	WOS:000255275800016
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2392460
专题	中国科学院大学
通讯作者	Liu, Cai-Ming
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,et al. A mercury(ii)-radical complex with a 1d ladder structure[J]. Journal of coordination chemistry,2008,61(8):1325-1332.
APA	Zhang, Jian-Ying,Liu, Cai-Ming,Zhang, De-Qing,&Zhu, Dao-Ben.(2008).A mercury(ii)-radical complex with a 1d ladder structure.Journal of coordination chemistry,61(8),1325-1332.
MLA	Zhang, Jian-Ying,et al."A mercury(ii)-radical complex with a 1d ladder structure".Journal of coordination chemistry 61.8(2008):1325-1332.

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