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Acidity and isomerization activity of sapo-11 synthesized by an improved hydrothermal method
Liu Ping1,2; Ren Jie1; Sun Yuhan1
刊名Chinese journal of catalysis
2008-04-01
卷号29期号:4页码:379-384
关键词Sapo-11 Hydrothermal synthesis Isopropanol Programmed temperature N-tetradecane Hydroisomerization
ISSN号0253-9837
通讯作者Liu ping()
英文摘要Medium-pore molecular sieve sapo-11 was synthesized using an improved hydrothermal method, which involves programmed heating of the synthesis gel in the presence of isopropanol. products were characterized using x-ray diffraction, scanning electron microscopy, n-2 adsorption, ammonia temperature-programmed desorption, infrared spectroscopy of adsorbed pyridine, and si-29 solid-state mas nmr. the results indicated that the sapo-11 sample synthesized by this method showed higher crystallinity, smaller particle size, and larger micropore volume than that prepared by the conventional hydrothermal method. furthermore, the numbers of total acid sites and medium strength acid sites were also enhanced. in the hydroisomerization of n-tetradecane, the pt/sapo-11 catalyst thus exhibited high activity and selectivity for isomers.
WOS关键词SILICOALUMINOPHOSPHATE MOLECULAR-SIEVES ; N-HEPTANE ; HYDROISOMERIZATION ; CONVERSION ; CATALYSTS ; PD
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
语种英语
出版者SCIENCE CHINA PRESS
WOS记录号WOS:000256048900014
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2390979
专题中国科学院大学
通讯作者Liu Ping
作者单位1.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China
2.Grad Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Liu Ping,Ren Jie,Sun Yuhan. Acidity and isomerization activity of sapo-11 synthesized by an improved hydrothermal method[J]. Chinese journal of catalysis,2008,29(4):379-384.
APA Liu Ping,Ren Jie,&Sun Yuhan.(2008).Acidity and isomerization activity of sapo-11 synthesized by an improved hydrothermal method.Chinese journal of catalysis,29(4),379-384.
MLA Liu Ping,et al."Acidity and isomerization activity of sapo-11 synthesized by an improved hydrothermal method".Chinese journal of catalysis 29.4(2008):379-384.
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