Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids | |
Wang, Duo-Sheng1; Chen, Qing-An1; Li, Wei2; Yu, Chang-Bin1; Zhou, Yong-Gui1; Zhang, Xumu2 | |
刊名 | journal of the american chemical society
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2010-07-07 | |
卷号 | 132期号:26页码:8909-+ |
通讯作者 | 周永贵 |
产权排序 | 1;1 |
英文摘要 | the first highly enantioselective hydrogenation of simple indoles was developed with a bronsted acid as an activator to form the iminium intermediate in situ, which was hydrogenated using pd(ococf(3))(2)/(r)-h8-binap catalyst system with up to 96% ee. the present method provides an efficient route to enantioenriched 2-substituted and 2,3-disubstituted indolines. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | highly enantioselective synthesis ; n-h imines ; heteroaromatic-compounds ; iridium catalysts ; derivatives ; quinolines ; indolines ; amination ; ketones |
收录类别 | SCI ; IC ; CCR |
原文出处 | false |
语种 | 英语 |
WOS记录号 | WOS:000279561200043 |
公开日期 | 2010-11-30 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/103499] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Rutgers State Univ, Dept Chem, Piscataway, NJ 08854 USA |
推荐引用方式 GB/T 7714 | Wang, Duo-Sheng,Chen, Qing-An,Li, Wei,et al. Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids[J]. journal of the american chemical society,2010,132(26):8909-+. |
APA | Wang, Duo-Sheng,Chen, Qing-An,Li, Wei,Yu, Chang-Bin,Zhou, Yong-Gui,&Zhang, Xumu.(2010).Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids.journal of the american chemical society,132(26),8909-+. |
MLA | Wang, Duo-Sheng,et al."Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids".journal of the american chemical society 132.26(2010):8909-+. |
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