Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids

	Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids
	Wang, Duo-Sheng 1; Chen, Qing-An 1; Li, Wei 2; Yu, Chang-Bin 1; Zhou, Yong-Gui 1; Zhang, Xumu 2
刊名	journal of the american chemical society
	2010-07-07
卷号	132 期号:26 页码:8909-+
通讯作者	周永贵
产权排序	1;1
英文摘要	the first highly enantioselective hydrogenation of simple indoles was developed with a bronsted acid as an activator to form the iminium intermediate in situ, which was hydrogenated using pd(ococf(3))(2)/(r)-h8-binap catalyst system with up to 96% ee. the present method provides an efficient route to enantioenriched 2-substituted and 2,3-disubstituted indolines.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	highly enantioselective synthesis ; n-h imines ; heteroaromatic-compounds ; iridium catalysts ; derivatives ; quinolines ; indolines ; amination ; ketones
收录类别	SCI ; IC ; CCR
原文出处	false
语种	英语
WOS记录号	WOS:000279561200043
公开日期	2010-11-30
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/103499]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Rutgers State Univ, Dept Chem, Piscataway, NJ 08854 USA
推荐引用方式 GB/T 7714	Wang, Duo-Sheng,Chen, Qing-An,Li, Wei,et al. Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids[J]. journal of the american chemical society,2010,132(26):8909-+.
APA	Wang, Duo-Sheng,Chen, Qing-An,Li, Wei,Yu, Chang-Bin,Zhou, Yong-Gui,&Zhang, Xumu.(2010).Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids.journal of the american chemical society,132(26),8909-+.
MLA	Wang, Duo-Sheng,et al."Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Bronsted Acids".journal of the american chemical society 132.26(2010):8909-+.