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Determination of benzhexol and procyclidine using an electrochemiluminescence-based sensor constructed by a screen-print technique
Qi, Bin1,2; Du, Yan1,2; Yang, Xiurong1
刊名Microchimica acta
2008-07-01
卷号162期号:1-2页码:211-217
关键词Screen-print Ru(bpy)(3)(2+) Nafion Electrochemiluminescence Benzhexol Procyclidine
ISSN号0026-3672
DOI10.1007/s00604-007-0843-7
通讯作者Yang, xiurong(xryang@ciac.jl.cl)
英文摘要A mass-producible electro-chemiluminescence (ecl)-based sensor was constructed by immobilizing tris(bipyridine)ruthenium(ii) (ru(bpy)(3)(2+)) on a carbon electrode using a screen-print (thick film) technique. the sensor was prepared by the following steps: first, the carbon ink was deposited to the epoxy substrate to form a conducting layer, then the mixture of carbon ink and nafion-ru(bpy)(3)(2+) composite was deposited onto the "working area" of this electrode. the last step was the formation of the nafion protecting polymer on the electrode surface. the sensor was characterized with tri-n-propylamine (tpa) as a co-reactant. the results indicated that the sensor exhibited an excellent electrochemical performance and ecl behaviour with good stability. the applications of the sensor to the ecl determination of benzhexol and procyclidine is reported.
WOS关键词TIN OXIDE ELECTRODES ; ELECTROGENERATED CHEMILUMINESCENCE ; COMPOSITE FILMS ; AMPEROMETRIC IMMUNOSENSOR ; ELECTROPHORESIS ; EMISSION ; NAFION ; ELECTROCHEMISTRY ; RU(BPY)(3)(2+) ; SEMICONDUCTOR
WOS研究方向Chemistry
WOS类目Chemistry, Analytical
语种英语
出版者SPRINGER WIEN
WOS记录号WOS:000257213200027
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2389012
专题中国科学院大学
通讯作者Yang, Xiurong
作者单位1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Jilin, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China
推荐引用方式
GB/T 7714
Qi, Bin,Du, Yan,Yang, Xiurong. Determination of benzhexol and procyclidine using an electrochemiluminescence-based sensor constructed by a screen-print technique[J]. Microchimica acta,2008,162(1-2):211-217.
APA Qi, Bin,Du, Yan,&Yang, Xiurong.(2008).Determination of benzhexol and procyclidine using an electrochemiluminescence-based sensor constructed by a screen-print technique.Microchimica acta,162(1-2),211-217.
MLA Qi, Bin,et al."Determination of benzhexol and procyclidine using an electrochemiluminescence-based sensor constructed by a screen-print technique".Microchimica acta 162.1-2(2008):211-217.
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