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	Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts
	Xiang, Minglin1,2; Li, Debao1; Xiao, Haicheng1,2; Zhang, Hanli1,2; Qi, Huijie1; Li, Wenhuai1; Zhong, Bing1; Sun, Yuhan1
刊名	Fuel
	2008-04-01
卷号	87期号:4-5页码:599-603
关键词	K/beta-mo2c Fischer-tropsch elements Higher alcohols synthesis
ISSN号	0016-2361
DOI	10.1016/j.fuel.2007.01.041
通讯作者	Li, debao(dbli@sxicc.ac.cn)
英文摘要	Fischer-tropsch elements (fe, co and ni) modified k/beta-mo2c catalysts were prepared and investigated for their performance in co hydrogenation. the results revealed that ni or co modified k/beta-mo2c catalysts were shown to be highly active and selective towards the synthesis of mixed alcohols, especially for the c2+oh production, but fe caused a negative effect. ni or co led to a decrease in apparent activation energies for c-1-c-4 alcohols, whereas fe caused a slight increase for methanol and the decrease for c-2-c-4 alcohols. as a result, the promotion effects of fischer-tropsch elements were different and followed the sequence: ni >> co > fe for the activity and ni >> co > fe for the c2+oh alcohol selectivity. (c) 2007 published by elsevier ltd.
WOS关键词	MOLYBDENUM CARBIDE CATALYSTS ; SYNTHESIS GAS ; CARBON-MONOXIDE ; MIXED ALCOHOLS ; PERFORMANCE ; HYDROGENATION ; CO
WOS研究方向	Energy & Fuels ; Engineering
WOS类目	Energy & Fuels ; Engineering, Chemical
语种	英语
出版者	ELSEVIER SCI LTD
WOS记录号	WOS:000253332200025
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2387809
专题	中国科学院大学
通讯作者	Li, Debao
作者单位	1.Chinese Acad Sci, Shanxi Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Xiang, Minglin,Li, Debao,Xiao, Haicheng,et al. Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts[J]. Fuel,2008,87(4-5):599-603.
APA	Xiang, Minglin.,Li, Debao.,Xiao, Haicheng.,Zhang, Hanli.,Qi, Huijie.,...&Sun, Yuhan.(2008).Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts.Fuel,87(4-5),599-603.
MLA	Xiang, Minglin,et al."Synthesis of higher alcohols from syngas over fischer-tropsch elements modified k/beta-mo2c catalysts".Fuel 87.4-5(2008):599-603.

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