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	Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine)
	Zhao Jun1,2; Xu Li1
刊名	Chinese journal of structural chemistry
	2008
卷号	27期号:6页码:687-690
关键词	Molybdenum Mixed-ligand Hydrogen bonds Crystal structure
ISSN号	0254-5861
通讯作者	Xu li(xli@fjirsm.ac.cn)
英文摘要	The novel mixed-ligand neutral compound mo3o4(c2o4)(2)center dot bipy(h2o)(3)]center dot etoh center dot 2h(2)o (bipy = 2,2'-bipyridine) has been prepared by the reaction of oxalic acid elution of mo(iv) and bipy, and characterized by single-crystal x-ray diffraction analysis and ir. the crystal is of triclinic, space groups p (1) over bar with a = 9.5520(2), b = 10.3730(1), c = 13.5722(2) angstrom, alpha = 74.940(12), beta = 80.772(14), gamma = 69.898(11)degrees, v = 1215.73(11) angstrom(3), z = 2, c16h24mo3n2o18, m-r = 820.19, d-c = 2.241 g/cm(3), mu = 1.616 mm(-1), f(000) = 808, t = 293(2) k, the final r = 0.0424 and wr = 0.0939 for 4119 observed reflections with i > 2 sigma(i). the trinuclear unit is coordinated by mixed ligands of oxalate and bipy. the intermolecular hydrogen bonding interactions among adjacent [mo3o4(c2o4)(2)center dot bipy(h2o)(3)] extend the compound into a three-dimensional supramolecular framework. the uncoordinated water molecules and ethal molecules act as space-fillers and consolidate the whole architecture through hydrogen bonding interactions.
WOS关键词	AQUEOUS MOLYBDENUM(IV) ; ISOTOPIC OXYGEN ; SYSTEMS
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000257348000010
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2387791
专题	中国科学院大学
通讯作者	Xu Li
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Zhao Jun,Xu Li. Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine)[J]. Chinese journal of structural chemistry,2008,27(6):687-690.
APA	Zhao Jun,&Xu Li.(2008).Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine).Chinese journal of structural chemistry,27(6),687-690.
MLA	Zhao Jun,et al."Synthesis and crystal structure of a new mixed-ligand cluster [mo3o4(c2o4)(2)bipy-(h2o)(3)]center dot etoh center dot 2h(2)o (bipy=2,2 '-bipyridine)".Chinese journal of structural chemistry 27.6(2008):687-690.

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