| A flexible 1,8-naphthyridyl derivative and its zn(ii) complexes: synthesis, structures, spectroscopic properties and recognition of cd(ii) | |
| Zhang, Hui-Miao1,2; Fu, Wen-Fu1,2,3; Gan, Xin3; Xu, Yan-Qing4,5; Wang, Jun1,2; Xu, Quan-Qing1,2; Chi, Shao-Ming1,2 | |
| 刊名 | Dalton transactions
 |
| 2008 | |
| 期号 | 47页码:6817-6824 |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/b809701a |
| 通讯作者 | Fu, wen-fu(wf_fu@yahoo.com.cn) |
| 英文摘要 | A flexible ligand bis(7-methyl-1,8-naphthyridine-2-ylamino) methane (l), having kappa(4)-chelating and kappa(2)-bridging modes, and its intriguing structural complexes of zn(ii) with mu-oh, kappa(1)-oac, mu-kappa(1)-oac and mu-kappa(2)-oac ligands, [zn(2)(l)(2)(oh)](clo(4))(3) (1), [zn(4)(l)(2)(oac)(6)(oh)(2)]center dot ch(2)cl(2) (2 center dot ch(2)cl(2)) and [zn(5)(l)(2)(oac)(10)](n)center dot 4nh(2)o(3 center dot 4h(2)o) were synthesized and their structures were determined by x-ray crystallography. these compounds exhibited intense blue fluorescent emissions with a lambda(max) in the range of 380-410 nm in ch(2)cl(2), ch(3)cn and ch(3)oh solutions, and solid-state emissions centered at 416, 463, 490 and 451 nm were observed for the compounds l, 1, 2 and 3 at room temperature, respectively. the investigated fluorescence properties of l associated with various metal ions showed that the fluorescence enhancement of l with cd(ii) was more sensitive than with other interfering cations. |
| WOS关键词 | CRYSTAL-STRUCTURE ; NAPHTHYRIDINE DIMER ; FLUORESCENT SENSORS ; ZINC(II) COMPLEX ; BINDING ; COORDINATION ; LIGAND ; PERCHLORATE ; CHEMISTRY ; DINUCLEAR |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000261742900017 |
| 内容类型 | 期刊论文 |
| URI标识 | http://www.corc.org.cn/handle/1471x/2385551 |
| 专题 | 中国科学院大学 |
| 通讯作者 | Fu, Wen-Fu |
| 作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, TIPC CAS, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Yunnan Normal Univ, Coll Chem & Engn, Kunming 650092, Peoples R China 4.Beijing Inst Technol, Inst Chem Phys, Beijing 100081, Peoples R China 5.Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Hui-Miao,Fu, Wen-Fu,Gan, Xin,et al. A flexible 1,8-naphthyridyl derivative and its zn(ii) complexes: synthesis, structures, spectroscopic properties and recognition of cd(ii)[J]. Dalton transactions,2008(47):6817-6824. |
| APA | Zhang, Hui-Miao.,Fu, Wen-Fu.,Gan, Xin.,Xu, Yan-Qing.,Wang, Jun.,...&Chi, Shao-Ming.(2008).A flexible 1,8-naphthyridyl derivative and its zn(ii) complexes: synthesis, structures, spectroscopic properties and recognition of cd(ii).Dalton transactions(47),6817-6824. |
| MLA | Zhang, Hui-Miao,et al."A flexible 1,8-naphthyridyl derivative and its zn(ii) complexes: synthesis, structures, spectroscopic properties and recognition of cd(ii)".Dalton transactions .47(2008):6817-6824. |
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