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	Dinuclear versus mononuclear zinc compounds from reduction of lzncl2 (l = alpha-diimine ligands): effects of the ligand substituent, reducing agent, and solvent
	Yu, Jie1,5; Yang, Xiao-Juan1,2; Liu, Yanyan1,5; Pu, Zhifeng3; Li, Qian-Shu3; Xie, Yaoming4; Schaefer, Henry F.4; Wu, Biao1,2
刊名	Organometallics
	2008-11-24
卷号	27期号:22页码:5800-5805
ISSN号	0276-7333
DOI	10.1021/om800405m
通讯作者	Yang, xiao-juan(yangxj@lzb.ac.cn)
英文摘要	A zn-zn-bonded compound, [k(thf)(2)](2)[(l-ipr)zn-zn(l-ipr)] (2) and three mononuclear zinc compounds, [zn(l-me)(2)na-2(et2o)(2)] (3), [zn(l-et)(2)na-2(thf)(2)] (4), and [zn(l-et)(2)k-2](n) (5), with n-aryl substituted alpha-diimine ligands l-ipr, l-me, and l-et (l = [(2,6-r2c6h3)n(me)c](2), r = pr-i, me, et, respectively) have been synthesized from the reduction of the lzncl2 precursors by the alkali metal na or k. x-ray structural analyses show that the compounds have a [zn2l2](2-) (2) or [znl2](2-) (3-5) core incorporating na+ or k+ ions solvated by thf or et2o molecules, except for 5, which displays a 2d polymeric structure formed by intermolecular k-c bonds due to the lack of k-solvent interactions. in compound 2, the formal zn2+ ion in the precursor is reduced to zn+, while in 3-5 it remains unreduced. the neutral ligands in the precursor, however, are doubly reduced to a dianion, l2-, in all compounds, as evidenced by the bond lengths of the n-c=c-n moiety of the ligands. effects of the ligand substituent, reducing agent, and solvent on the products have been studied, which reveal that the steric bulk of the ligand is the most important factor that determines whether the zn-zn bond can be formed. dft computations show that the zn-zn bond in 2 is formed mainly by the 4s orbitals of zinc. the results of natural charge and orbital analyses also confirm the reduction of the ligands to their dianionic forms.
WOS关键词	ZN-ZN BONDS ; MOLECULAR-STRUCTURE ; STABLE COMPOUND ; COMPLEXES ; SERIES ; ZN-2(ETA(5)-C5ME5)(2) ; CHEMISTRY
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear ; Chemistry, Organic
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000260791400008
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2385491
专题	中国科学院大学
通讯作者	Yang, Xiao-Juan
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 3.Beijing Inst Technol, Inst Chem Phys, Beijing 100081, Peoples R China 4.Univ Georgia, Dept Chem, Ctr Computat Chem, Athens, GA 30602 USA 5.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Yu, Jie,Yang, Xiao-Juan,Liu, Yanyan,et al. Dinuclear versus mononuclear zinc compounds from reduction of lzncl2 (l = alpha-diimine ligands): effects of the ligand substituent, reducing agent, and solvent[J]. Organometallics,2008,27(22):5800-5805.
APA	Yu, Jie.,Yang, Xiao-Juan.,Liu, Yanyan.,Pu, Zhifeng.,Li, Qian-Shu.,...&Wu, Biao.(2008).Dinuclear versus mononuclear zinc compounds from reduction of lzncl2 (l = alpha-diimine ligands): effects of the ligand substituent, reducing agent, and solvent.Organometallics,27(22),5800-5805.
MLA	Yu, Jie,et al."Dinuclear versus mononuclear zinc compounds from reduction of lzncl2 (l = alpha-diimine ligands): effects of the ligand substituent, reducing agent, and solvent".Organometallics 27.22(2008):5800-5805.

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