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	Preparation and luminescence properties of covalent linking of luminescent ternary europium complexes on periodic mesoporous organosilica
	Guo, Xianmin1,2; Wang, Xiaomei1,2; Zhang, Hongjie1; Fu, Lianshe3; Guo, Huadong1,2; Yu, Jiangbo1; Carlos, L. D.3; Yang, Kuiyue1
刊名	Microporous and mesoporous materials
	2008-12-01
卷号	116期号:1-3页码:28-35
关键词	Organic/inorganic hybrids Periodic mesoporous organosilica Lanthanide complex Photoluminescence
ISSN号	1387-1811
DOI	10.1016/j.micromeso.2008.03.007
通讯作者	Zhang, hongjie(hongjie@ciac.jl.cn)
英文摘要	A novel periodic mesoporous organosilica (pmo) covalently grafting with phen (phen-pmo, phen = 1, 10-phenanthroline) was synthesized via a co-condensation of 1,2-bis(triethoxysilyl)ethane (btese) and 5, 6-bis(n-3-(triethoxysilyl)propyl)ureyl-1, 10-phenanthroline (phen-si) using supramolecular polyoxyethylene (10) stearyl ether (brij 76) surfactant as template (under acidic conditions). accordingly, a series of pmo materials (pmos) containing eu(tta)(3)phen (denoted as eu(tta)(3)phen-pmo, tta = 2-thenoyltrifluoroacetone) were synthesized by impregnation of eu(tta)(3)center dot 2h(2)o into phen-pmo through a ligand exchange reaction. for comparison, euphen-pmo was also prepared using the same approach except eucl(3) - 6h(2)o instead of eu(tta)(3)center dot 2h(2)o. the mesostructures of the pmo materials were characterized by xrd, n(2) adsorption-desorption and tem measurements. the results showed that during the surfactant extraction process, the chelating organic ligand structure was preserved, which was confirmed by fourier transform infrared (ftir) and (29)si cp-mas nmr spectroscopies. under uv irradiation, eu(tta)3phen-pmo exhibited the characteristic emission of eu(3+) ions. based on the emission spectra, the experiment intensity parameters for eu(tta)(3)phen, euphen-pmo and eu(tta)(3)phen-pmo were calculated according to judd-ofelt theory. compared to the pure complex, the resulting hybrid material exhibited better thermal stability and similar emission quantum efficiency, demonstrated by thermogravimetric analysis and luminescence characterization, respectively. the hybrid material eu(tta)(3)phen-pmo showed higher emission quantum efficiency than that of euphen-pmo, indicating that tta is an efficient sensitizer for the luminescence of central eu(3+) ions. (c) 2008 elsevier inc. all rights reserved.
WOS关键词	ORGANIC-INORGANIC HYBRIDS ; BETA-DIKETONATE COMPLEX ; INTRAMOLECULAR ENERGY-TRANSFER ; RARE-EARTH IONS ; THIN-FILMS ; LARGE-PORE ; IN-SITU ; LANTHANIDE COMPLEXES ; SILICA MATRIX ; ACCESSIBILITY
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000261133600005
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2384145
专题	中国科学院大学
通讯作者	Zhang, Hongjie
作者单位	1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China 3.Univ Aveiro, CICECO, Dept Phys, P-3810193 Aveiro, Portugal
推荐引用方式 GB/T 7714	Guo, Xianmin,Wang, Xiaomei,Zhang, Hongjie,et al. Preparation and luminescence properties of covalent linking of luminescent ternary europium complexes on periodic mesoporous organosilica[J]. Microporous and mesoporous materials,2008,116(1-3):28-35.
APA	Guo, Xianmin.,Wang, Xiaomei.,Zhang, Hongjie.,Fu, Lianshe.,Guo, Huadong.,...&Yang, Kuiyue.(2008).Preparation and luminescence properties of covalent linking of luminescent ternary europium complexes on periodic mesoporous organosilica.Microporous and mesoporous materials,116(1-3),28-35.
MLA	Guo, Xianmin,et al."Preparation and luminescence properties of covalent linking of luminescent ternary europium complexes on periodic mesoporous organosilica".Microporous and mesoporous materials 116.1-3(2008):28-35.

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