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	Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n)
	Wang Jian; Huang Mei-Hua; Liu Ping; Cheng Wen-Dan; Zhang Li-Mei
刊名	Chinese journal of structural chemistry
	2007
卷号	26期号:2页码:139-142
关键词	Crystal structure Manganese complex Eight-membered ring One-dimensional chain
ISSN号	0254-5861
通讯作者	Liu ping(pliu@fjirsm.ac.cn)
英文摘要	The title compound, [mn-2(.)(dinitrobenzoic acid)(4)(.)(1,10-phen)(2)](n), has a linear chain structure containing binuclear [mn2(.)(dinitrobenzoic acid)4(1,10-phen)2] repeat units. it crystallizes in the triclinic system, space group p (1) over bar with a = 7.9261(8), b = 12.1329(15), c = 14.847(2) angstrom, alpha = 103.845(5), beta = 101.424(5), gamma = 92.618(4), m-r = 657.37, v = 1352.3(2) angstrom(3), z = 2, d-c = 1.614 g/cm(3), f(000) = 666, mu = 0.567 min(-1), the final r = 0.0407 and wr = 0.1015 for 4081 observed reflections with i > 2 sigma(i). the mn atom is six-coordinated by two n and four o atoms, forming a slightly distorted octahedral geometry. all mn-o and mn-n bond distances range from 2.093(2) to 2.310(2) angstrom. two adjacent octahedral units are bridged together by two pairs of bi-monodentate carboxyl groups of different dinitrobenzoic acids to form an eight-membered ring with chair-typed configuration, thus generating a one-dimensional chain along the a axis.
WOS关键词	BIOLOGICAL RELEVANCE
WOS研究方向	Chemistry ; Crystallography
WOS类目	Chemistry, Inorganic & Nuclear ; Crystallography
语种	英语
出版者	CHINESE JOURNAL STRUCTURAL CHEMISTRY
WOS记录号	WOS:000244505000002
内容类型	期刊论文
URI标识	http://www.corc.org.cn/handle/1471x/2383898
专题	中国科学院大学
通讯作者	Liu Ping
作者单位	1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Wang Jian,Huang Mei-Hua,Liu Ping,et al. Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n)[J]. Chinese journal of structural chemistry,2007,26(2):139-142.
APA	Wang Jian,Huang Mei-Hua,Liu Ping,Cheng Wen-Dan,&Zhang Li-Mei.(2007).Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n).Chinese journal of structural chemistry,26(2),139-142.
MLA	Wang Jian,et al."Synthesis and structure of a manganese(ii) complex: [mn-2 center dot(dinitrobenzoic acid)(4)center dot(1,10-phen)(2)](n)".Chinese journal of structural chemistry 26.2(2007):139-142.

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